http://www.cnr.it/ontology/cnr/individuo/prodotto/ID39250
Jones birefringence in gases. Ab initio electron correlated results for atoms and linear molecules. (Articolo in rivista)
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- Label
- Jones birefringence in gases. Ab initio electron correlated results for atoms and linear molecules. (Articolo in rivista) (literal)
- Anno
- 2003-01-01T00:00:00+01:00 (literal)
- Alternative label
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
- Rizzo A., Coriani S. (literal)
- Pagina inizio
- Pagina fine
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
- Note
- ISI Web of Science (WOS) (literal)
- Titolo
- Jones birefringence in gases. Ab initio electron correlated results for atoms and linear molecules. (literal)
- Abstract
- The results of an ab initio investigation of the Jones
birefringence (JB) of noble gases (He, Ne, Ar, Kr) and of a few
linear molecules -- both centrosymmetric (H$_2$, N$_2$,
C$_2$H$_2$) and dipolar (CO) -- carried out employing Coupled
Cluster response techniques and rather extended correlation
consistent basis sets are presented. The relationships existing
between the appropriate linear, quadratic and cubic frequency
dependent response functions and the tensors introduced in the
theoretical derivation of the anisotropy by Graham and Raab in
1983 [ Proc. R. Soc. Lon. A, {\bf{390}}, 73, (1983)] are
introduced. The magnitude of the effect is determined and
comparison is made with that of the Cotton---Mouton effect (CME),
which, together with the Kerr effect, is closely related to Jones
birefringence and superimposed to it in actual measurements, and
of electric field gradient induced birefringence (EFGB). CME
yields anisotropies of the refractive index $\approx0 to
$\approx00 larger than those predicted for JB in the eight
systems studied, whereas EFGB and JB are shown to be of comparable
strength. (literal)
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