Neodymium beta-diketonate glyme complexes: Synthesis and characterization of volatile precursors for MOCVD applications (Articolo in rivista)

Type

• Prodotto della ricerca (Classe)
• Articolo in rivista (Classe)

Label

• Neodymium beta-diketonate glyme complexes: Synthesis and characterization of volatile precursors for MOCVD applications (Articolo in rivista) (literal)

Anno

• 2009-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1016/j.ica.2009.05.044 (literal)

Alternative label

• Lo Nigro R, Toro RG, Fragala ME, Rossi P, Dapporto P, Malandrino G (2009)
  Neodymium beta-diketonate glyme complexes: Synthesis and characterization of volatile precursors for MOCVD applications
  in Inorganica Chimica Acta (Testo stamp.)
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Lo Nigro R, Toro RG, Fragala ME, Rossi P, Dapporto P, Malandrino G (literal)

Pagina inizio

• 4623 (literal)

Pagina fine

• 4629 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 362 (literal)

Rivista

• Inorganica Chimica Acta (Rivista)

Note

• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• 1. Univ Catania, CNR, ISTM, Dipartimento Sci Chim, I-95125 Catania, Italy 2. UdR Catania, INSTM, I-95125 Catania, Italy 3. CNR, IMM, I-95121 Catania, Italy 4. Univ Florence, Dipartimento Energet S Stecco, I-50136 Florence, Italy (literal)

Titolo

• Neodymium beta-diketonate glyme complexes: Synthesis and characterization of volatile precursors for MOCVD applications (literal)

Abstract

• The monoglyme [CH3OCH2CH2OCH3] and diglyme [CH3O(CH2CH2O)(2)CH3] adducts of the neodymium tris-hexauoroacetylacetonato [Nd(hfa)(3)center dot monoglyme center dot H2O and Nd(hfa)(3)center dot diglyme] have been synthesised in a single step reaction. They have been characterized by elemental analyzes, mass spectrometry, and IR spectroscopy. Single crystal X-ray diffraction studies provide evidence of a mononuclear nine-coordinated complex with a monocapped square antiprismatic structure for the Nd(hfa)(3)center dot diglyme (monoclinic system, space group P2(1)/n; a = 9.7717(2), b = 15.5723(4), c = 20.5620(5)angstrom, beta = 103.668(2)degrees; Z = 4). The Nd(hfa)(3)center dot monoglyme center dot H2O consists of asymmetric units containing two similar molecules (monoclinic system, space group = C2; a = 16.7057(4), b = 12.2579(4), c = 29.3734(5)angstrom, beta = 101.170(3)degrees, Z = 8). The mass transport properties of these adducts have been investigated by thermogravimetric analysis which revealed high volatility and good thermal stability with a residue left lower than 3%. The Nd(hfa)(3)center dot diglyme has been successfully applied to the low-pressure metal organic chemical vapor deposition (MOCVD) of NdBa2Cu3O7 (delta) thin films. (literal)

Prodotto di

• Institute for microelectronics and microsystems (IMM) (Istituto)
• Materiali multifunzionali, e innovativi per componenti integrati (MD.P05.003.002) (Modulo)

Autore CNR

• RAFFAELLA LO NIGRO (Unità di personale interno)
• ROBERTA GRAZIA TORO (Unità di personale interno)

Insieme di parole chiave

• Keywords of "Neodymium beta-diketonate glyme complexes: Synthesis and characterization of volatile precursors for MOCVD applications" (Insieme di parole chiave)

Incoming links:

Prodotto

• Institute for microelectronics and microsystems (IMM) (Istituto)
• Materiali multifunzionali, e innovativi per componenti integrati (MD.P05.003.002) (Modulo)

Autore CNR di

• RAFFAELLA LO NIGRO (Unità di personale interno)
• ROBERTA GRAZIA TORO (Unità di personale interno)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Inorganica Chimica Acta (Rivista)

Insieme di parole chiave di

• Keywords of "Neodymium beta-diketonate glyme complexes: Synthesis and characterization of volatile precursors for MOCVD applications" (Insieme di parole chiave)