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The Relaxation of vibrationally excited O2 molecules by atomic oxygen (Articolo in rivista)
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- Label
- The Relaxation of vibrationally excited O2 molecules by atomic oxygen (Articolo in rivista) (literal)
- Anno
- 2007-01-01T00:00:00+01:00 (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
- 10.1016/j.cplett.2007.06.099 (literal)
- Alternative label
F. Esposito; M. Capitelli (2007)
The Relaxation of vibrationally excited O2 molecules by atomic oxygen
in Chemical physics letters (Print); ELSEVIER SCIENCE BV, PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS, AMSTERDAM (Paesi Bassi)
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- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
- F. Esposito; M. Capitelli (literal)
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- http://www.sciencedirect.com/science/article/pii/S0009261407008585 (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
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- ISI Web of Science (WOS) (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
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- Titolo
- The Relaxation of vibrationally excited O2 molecules by atomic oxygen (literal)
- Abstract
- A complete set of V-T (vibration-translation) relaxation rates of vibrationally excited oxygen molecules by parent atoms has been obtained by running quasiclassical trajectories on an accurate potential energy surface. The results have been validated by comparing them with old and new experimental data. Satisfactory agreement has been obtained with recent low temperature experimental data. Comparison with older rate coefficients obtained at higher temperature prompts the elaboration of new experiments not based on the application of models restricted to monoquantum transitions. It is in fact apparent from the calculations the importance of multiquantum processes. (literal)
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