Adsorption of 2,3-butanediol on Si(100) (Articolo in rivista)

Type
Label
  • Adsorption of 2,3-butanediol on Si(100) (Articolo in rivista) (literal)
Anno
  • 2004-01-01T00:00:00+01:00 (literal)
Alternative label
  • J.W. Kim, M. Carbone, M. Tallarida, J.H. Dil, K. Horn, M.P. Casaletto, R. Flammini, M.N. Piancastelli (2004)
    Adsorption of 2,3-butanediol on Si(100)
    in Surface science
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • J.W. Kim, M. Carbone, M. Tallarida, J.H. Dil, K. Horn, M.P. Casaletto, R. Flammini, M.N. Piancastelli (literal)
Pagina inizio
  • 179 (literal)
Pagina fine
  • 185 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 559 (literal)
Rivista
Note
  • ISI Web of Science (WOS) (literal)
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  • a Department of Molecular Physics, Fritz-Haber-Institut der Max-Planck-Gesellschaft, Faradayweg 4-6, 14195 Berlin, Germany b Dip. Di Scienze e Tecnologie Chimiche e INFM, Universita Tor Vergata, 00133 Roma, Italy c Istituto per lo Studio di Materiali Nanostrutturati, ISMN, 90146 Palermo, Italy d Istituto di Metodologie Inorganiche e dei Plasmi, CNR, 00010 Monterotondo Scalo, Italy (literal)
Titolo
  • Adsorption of 2,3-butanediol on Si(100) (literal)
Abstract
  • The adsorption of 2,3-butanediol on a Si(1 0 0) surface has been investigated by photoelectron spectroscopy. The valence band spectra show features assigned to molecular orbitals of 2,3-butanediol by comparison with calculations, and the surface states of clean Si are removed. The Si 2p reveals core-level shifts with two new components at 0.24 andc0.97 eV from the bulk, which are assigned to Si-H and Si-O bonds, respectively. The C 1s core-level spectrum consists of two major peaks separated by 1.3 eV, which are attributed to carbon atoms in -CHOH and -CHcgroups, in thecmolecule respectively. From the analysis of the valence band, the Si 2p, C 1s, and O 1s core-level spectra, we concludecthat the 2,3-butanediol molecule undergoes a cleavage of the O-H bonds, and is bonded to the surface by the oxygencatoms. The molecule shows no further fragmentation and probably forms a six-membered ring of the O-C-C-Osegment with the Si dimer atoms. (literal)
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