Hydrogen abstraction from H-donor substrates by the 6-CF3-benzotriazol-N-oxyl radical (TFNO) (Articolo in rivista)

Type

• Prodotto della ricerca (Classe)
• Articolo in rivista (Classe)

Label

• Hydrogen abstraction from H-donor substrates by the 6-CF3-benzotriazol-N-oxyl radical (TFNO) (Articolo in rivista) (literal)

Anno

• 2011-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1002/poc.1783 (literal)

Alternative label

• M. A. Tadesse, C. Galli, P. Gentili (2011)
  Hydrogen abstraction from H-donor substrates by the 6-CF3-benzotriazol-N-oxyl radical (TFNO)
  in Journal of physical organic chemistry (Print); John Wiley & Sons Ltd., Chichester (Regno Unito)
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• M. A. Tadesse, C. Galli, P. Gentili (literal)

Pagina inizio

• 529 (literal)

Pagina fine

• 538 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#url

• http://onlinelibrary.wiley.com/ (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 24 (literal)

Rivista

• Journal of physical organic chemistry (Rivista)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#pagineTotali

• 10 (literal)

Note

• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• Department of Chemistry and IMC-CNR Sezione Meccanismi di Reazione, Universita` 'La Sapienza', Roma, Italy (literal)

Titolo

• Hydrogen abstraction from H-donor substrates by the 6-CF3-benzotriazol-N-oxyl radical (TFNO) (literal)

Abstract

• The aminoxyl radical 6-trifluoromethyl-benzotriazol-N-oxyl (TFNO) has been generated from the parent hydroxylamine 6-CF3-1-hydroxy-benzotriazole (TFBT) by one-electron oxidation with a CeIV salt and characterized by spectrophotometry and cyclic voltammetry (CV). Rate constants of H-abstraction (kH) by TFNO from a number of H-donor benzylic substrates have been determined spectrophotometrically in MeCN solution at 25 -C. A radical H-atom transfer (HAT) route of oxidation is substantiated for TFNO by several pieces of evidence. The kinetic data also testify the relevance of stereoelectronic effects upon the HAT reactivity of TFNO. (literal)

Editore

• John Wiley & Sons Ltd. (Editore)

Prodotto di

• Istituto di metodologie chimiche (IMC) (Istituto)

Autore CNR

• CARLO GALLI (Persona)
• PATRIZIA GENTILI (Persona)
• Mahelet Aweke Tadesse (Persona)

Insieme di parole chiave

• Keywords of "Hydrogen abstraction from H-donor substrates by the 6-CF3-benzotriazol-N-oxyl radical (TFNO)" (Insieme di parole chiave)

Incoming links:

Prodotto

• Istituto di metodologie chimiche (IMC) (Istituto)
• http://www.cnr.it/ontology/cnr/individuo/modulo/ID6932

Autore CNR di

• PATRIZIA GENTILI (Persona)
• CARLO GALLI (Persona)
• Mahelet Aweke Tadesse (Persona)

Editore di

• John Wiley & Sons Ltd. (Editore)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Journal of physical organic chemistry (Rivista)

Insieme di parole chiave di

• Keywords of "Hydrogen abstraction from H-donor substrates by the 6-CF3-benzotriazol-N-oxyl radical (TFNO)" (Insieme di parole chiave)