http://www.cnr.it/ontology/cnr/individuo/prodotto/ID33385
Hydrogen Abstraction and Electron Transfer with Aminoxyl Radicals: Synthetic and Mechanistic Issue (Articolo in rivista)
- Type
- Label
- Hydrogen Abstraction and Electron Transfer with Aminoxyl Radicals: Synthetic and Mechanistic Issue (Articolo in rivista) (literal)
- Anno
- 2008-01-01T00:00:00+01:00 (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
- 10.1002/anie.200704292 (literal)
- Alternative label
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
- Galli C.; Gentili P.; Lanzalunga O. (literal)
- Pagina inizio
- Pagina fine
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
- Rivista
- Note
- ISI Web of Science (WOS) (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
- Dipartimento di Chimica, Università \"La Sapienza\" and
Istituto di Metodologie Chimiche (IMC-CNR)
Sezione Meccanismi di Reazione
P.le A. Moro 5, 00185 Roma, Italy (literal)
- Titolo
- Hydrogen Abstraction and Electron Transfer with Aminoxyl Radicals: Synthetic and Mechanistic Issue (literal)
- Abstract
- Aminoxyl radicals are a valuable class of reactive intermediates
with interesting synthetic and reactivity properties. This
Minireview summarizes salient synthetic results obtained in radical
oxidations using aminoxyl radicals, and then focuses on reactivity
issues arising from recent literature surveys. The structural and reactivity features of the aminoxyl radical and substrate provides a possible
explanation of the double reactivity of the aminoxyl radicals. This
mechanistic dichotomy between H-atom abstraction and electron abstraction
routes is highlighted in this Minireview. (literal)
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- Autore CNR
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