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Determination of sertraline and N-desmethylsertraline in human plasma by CE with LIF detection (Articolo in rivista)
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- Determination of sertraline and N-desmethylsertraline in human plasma by CE with LIF detection (Articolo in rivista) (literal)
- Anno
- 2007-01-01T00:00:00+01:00 (literal)
- Alternative label
A. Musenga, E. Kenndler, L. Marcolini, M. Amore, S. Fanali, M. A. Raggi (2007)
Determination of sertraline and N-desmethylsertraline in human plasma by CE with LIF detection
in Electrophoresis (Weinh., Print)
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- A. Musenga, E. Kenndler, L. Marcolini, M. Amore, S. Fanali, M. A. Raggi (literal)
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- ISI Web of Science (WOS) (literal)
- Titolo
- Determination of sertraline and N-desmethylsertraline in human plasma by CE with LIF detection (literal)
- Abstract
- A method has been developed for the analysis of the antidepressant dru gsertraline together
with its main metabolite N-desmethylsertraline (DMS) in human plasma. It Is based on CE
with LIF detection (488nm). A SPE procedure is employed for biological sample pretreatment, followed by a derivatization step with FITC; reboxetine was the internal standard
The effect of CD, acetone and N-methyl-D-glucamine (GLC) as constituents of the BGE
for analyte separation was investigated. The final BGE consisted of 20mM carbonate buffer,
pH9.0, with2.5 mM heptakis(2,6-di-O-methyl)-b-CD, 50mM GLC and 20% v/v acetone.
With 30kV applied voltage, the electrophoretic run is completed in7.5min. Linearity was
observed in the plasma concentration range from 3.0 to 500 ng/mL for sertraline and 4.0 to
500ng/mL for DMS. Extraction yield was higher than 97.1%,precision expressed as RSD% was
lower 3.7, accuracy (recovery) was higher than 95.6%. Due to its sensitivity and selectivity, the method was suited for the analysis of plasma samples from patients undergoing therapy with sertraline.
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