http://www.cnr.it/ontology/cnr/individuo/prodotto/ID33119
Chiral HPLC Resolution of Neutral Pesticides (Articolo in rivista)
- Type
- Label
- Chiral HPLC Resolution of Neutral Pesticides (Articolo in rivista) (literal)
- Anno
- 2004-01-01T00:00:00+01:00 (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
- 10.1081/JLC-120027085 (literal)
- Alternative label
Chiara M. Polcaro , Antonio Berti , Luisa Mannina, Carolina Marra, Massimo Sinibaldi , Stéphane Viel (2004)
Chiral HPLC Resolution of Neutral Pesticides
in Journal of liquid chromatography & related technologies (Print); Taylor & Francis Group, London (Regno Unito)
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- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
- Chiara M. Polcaro , Antonio Berti , Luisa Mannina, Carolina Marra, Massimo Sinibaldi , Stéphane Viel (literal)
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- Note
- ISI Web of Science (WOS) (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
- Luisa Mannina Università degli studi del Molise,Dipartimento S.T.A.A.M, Facoltà di Agraria, Campobasso, Italy
Carolina Marra IMC CNR
Stephane Viel IMC CNR (literal)
- Titolo
- Chiral HPLC Resolution of Neutral Pesticides (literal)
- Abstract
- The direct HPLC resolution of two synthetic neutral pesticides, Metolachlor and Ethofumesate, was studied on silica gel coated with cellulose tris-(3,5-dimethylphenylcarbamate) derivative (Chiracel OD-H). The specific composition of the mobile phase has allowed the full separation of the four Metolachlor stereoisomers, which had not previously been resolved on other chiral stationary phases. The isomer elution sequence of both resolved pesticides was determined by 1H NMR and polarimetric analyses. The chromatographic system, coupled with mass-spectrometric detection, was used to determine the isomeric ratio of Metolachlor stereoisomers after incubation in soil. (literal)
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