Phase Transitions in Aqueous triblock copolymers: NMR relaxation studies (Articolo in rivista)

Type
Label
  • Phase Transitions in Aqueous triblock copolymers: NMR relaxation studies (Articolo in rivista) (literal)
Anno
  • 2003-01-01T00:00:00+01:00 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
  • 10.1007/s00396-003-0888-z (literal)
Alternative label
  • Iovino A., La Mesa C., Capitani D., Segre A.L. (2003)
    Phase Transitions in Aqueous triblock copolymers: NMR relaxation studies
    in Colloid and polymer science (Print)
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Iovino A., La Mesa C., Capitani D., Segre A.L. (literal)
Pagina inizio
  • 1136 (literal)
Pagina fine
  • 1141 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#url
  • http://dx.doi.org/10.1007/s00396-003-0888-z (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 281 (literal)
Rivista
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#pagineTotali
  • 6 (literal)
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  • Articolo Scientifico in cui tramite misure rilassometriche si caratterizza un copolimero a blocchi in relazione al suo comportamento in soluzione acquosa. (literal)
Note
  • Scopu (literal)
  • ISI Web of Science (WOS) (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • Istituto di Metodologie Chimiche Dipartimento di Chimica, Sapienza Università di Roma (literal)
Titolo
  • Phase Transitions in Aqueous triblock copolymers: NMR relaxation studies (literal)
Abstract
  • Longitudinal NMR relaxation times were used to investigate the thermal transitions occurring in an aqueous triblock copolymer of the poly(oxyethylene)–poly(oxypropylene)–poly(oxyethylene) family. In such a system molecule–micelle and micelle–liquid crystal transitions are observed, depending on temperature and composition. The longitudinal relaxation time, R 1, significantly changes when the aforementioned phase transitions take place. In the case of molecule–micelle equilibrium, changes in R 1 values of the methyl (and methynic) group signal, located in the lipophilic portion of block copolymers, are observed. The effect is ascribed to a significant dehydration of the poly(oxypropylene) chains, as a consequence of micelle formation. Conversely, the thermal transitions from micelles to liquid-crystalline phases are associated with significant changes in the relaxation time of poly(oxyethylene) units. The latter effect is tentatively ascribed to a partial dehydration and/or interdigitation of the poly(oxyethylene) moieties in the block copolymer. (literal)
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