Oxidative Addition of Methyl Iodide and CO Migratory Insertion in a Cationic Rhodium Complex of a S,N,S Tridentate Ligand (Articolo in rivista)

Type
Label
  • Oxidative Addition of Methyl Iodide and CO Migratory Insertion in a Cationic Rhodium Complex of a S,N,S Tridentate Ligand (Articolo in rivista) (literal)
Anno
  • 2003-01-01T00:00:00+01:00 (literal)
Alternative label
  • Bassetti M., Capone A., Mastrofrancesco L., Salamone M. (2003)
    Oxidative Addition of Methyl Iodide and CO Migratory Insertion in a Cationic Rhodium Complex of a S,N,S Tridentate Ligand
    in Organometallics
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Bassetti M., Capone A., Mastrofrancesco L., Salamone M. (literal)
Pagina inizio
  • 2535 (literal)
Pagina fine
  • 2538 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 22 (literal)
Rivista
Note
  • ISI Web of Science (WOS) (literal)
Titolo
  • Oxidative Addition of Methyl Iodide and CO Migratory Insertion in a Cationic Rhodium Complex of a S,N,S Tridentate Ligand (literal)
Abstract
  • The cationic rhodium(I) carbonyl complex mer-[Rh(L)(CO)]PF6 coordinated by a tridentate S,N,S donor ligand (L = 2,6-bis(benzylthiomethyl)pyridine) reacts with MeI to give the corresponding acetyl derivative [Rh(L)(COMe)I]PF6, by consecutive oxidative addition-migratory insertion reactions via observable methyl-rhodium(III) intermediate complexes. Rate constants and activation parameters have been obtained for both reaction steps in MeCN, and compared with those of complexes coordinated by mono and bi-dentate ligands. This is the first report on the organometallic reactivity of a rhodium(I) carbonyl complex of S,N,S ligands. (literal)
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