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Tridentate (NNO) Schiff-base copper(II) complex: synthesis, crystalstructure, and magnetic study (Articolo in rivista)
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- Label
- Tridentate (NNO) Schiff-base copper(II) complex: synthesis, crystalstructure, and magnetic study (Articolo in rivista) (literal)
- Anno
- 2009-01-01T00:00:00+01:00 (literal)
- Alternative label
Adhikary C.; Sen R.; Bocelli G.; Cantoni A.; Solzi M.; Chaudhuri S.; Koner S. (2009)
Tridentate (NNO) Schiff-base copper(II) complex: synthesis, crystalstructure, and magnetic study
in Journal of coordination chemistry (Print)
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- Adhikary C.; Sen R.; Bocelli G.; Cantoni A.; Solzi M.; Chaudhuri S.; Koner S. (literal)
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- In: Journal of Coordination Chemistry, vol. 62 (22) pp. 3573 - 3582. Taylor & Francis, 2009. (literal)
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- ISI Web of Science (WOS) (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
- Department of Chemistry, Jadavpur University, Jadavpur, India, CNR-IMEM, Parma, Department of Physics, University of Parma, Parma, Italy, SAIF, Bose Institute, India (literal)
- Titolo
- Tridentate (NNO) Schiff-base copper(II) complex: synthesis, crystalstructure, and magnetic study (literal)
- Abstract
- A new azido adduct of a tridentate Schiff-base copper(II) complex has been synthesized and characterized structurally and magnetically. X-ray single crystal structure analysis reveals that the asymmetric unit of [Cu2(L)2(µ1,1-N3)2][Cu(L)(N3)] (1) [HL = 1-(N-ortho-hydroxyacetophenimine)-2,2-diethyl-aminoethane] has two independent moieties. One of these forms a dimer, containing end-on azido bridges, with its center of inversion related equivalents. The complex crystallizes in monoclinic space group P21/c with a = 10.112(2), b = 31.938(4), c = 9.718(2) Aring and ² = 95.00(2)°. Variable temperature magnetic susceptibility data show antiferromagnetic interactions between copper(II) centers. (literal)
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