Organometallic red-emitting chromophores: a computational and experimental study on cyclometallated Nile Red complexes of palladium(II) and platinum(II) acetylacetonates and hexafluoroacetylacetonates (Articolo in rivista)

Type
Label
  • Organometallic red-emitting chromophores: a computational and experimental study on cyclometallated Nile Red complexes of palladium(II) and platinum(II) acetylacetonates and hexafluoroacetylacetonates (Articolo in rivista) (literal)
Anno
  • 2008-01-01T00:00:00+01:00 (literal)
Alternative label
  • Pugliese, T; Godbert, N; Aiello, I; La Deda, M; Ghedini, M; Amati, M; Belviso, S; Lelj, F (2008)
    Organometallic red-emitting chromophores: a computational and experimental study on cyclometallated Nile Red complexes of palladium(II) and platinum(II) acetylacetonates and hexafluoroacetylacetonates
    in Dalton transactions (2003. Print)
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Pugliese, T; Godbert, N; Aiello, I; La Deda, M; Ghedini, M; Amati, M; Belviso, S; Lelj, F (literal)
Pagina inizio
  • 6563 (literal)
Pagina fine
  • 6572 (literal)
Rivista
Note
  • ISI Web of Science (WOS) (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • \"[Pugliese, Teresa; Godbert, Nicolas; La Deda, Massimo; Ghedini, Mauro] Univ Calabria, Dipartimento Chim, Ctr Eccelenza CEMIF CAL LASCAMM, CR INSTM Unita Calabria & Licryl, I-87036 Arcavacata Di Rende, CS, Italy; [Amati, Mario; Belviso, Sandra; Lelj, Francesco] Univ Basilicata, Dipartimento Chim, LASCAMM, CR INSTM Unita Basilicata & LaMI, I-85100 Potenza, Italy (literal)
Titolo
  • Organometallic red-emitting chromophores: a computational and experimental study on cyclometallated Nile Red complexes of palladium(II) and platinum(II) acetylacetonates and hexafluoroacetylacetonates (literal)
Abstract
  • A comparative photophysical, electrochemical and computational study of a series of Nile Red cyclopalladated and newly synthesised cycloplatinated complexes is reported. All complexes are luminescent at room temperature and the emission properties are governed by the nature of the cyclometallated dye. However, the presence of platinum(II) as metal centre decreases severely the emission quantum yield, while the electronegativity of the ancillary hexafluoroacetylacetonato ligand enhanced the emission properties of the Nile Red complexes. (literal)
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