Detailed analysis of dynamic mechanical properties of TPU nanocomposite: The role of the interfaces (Articolo in rivista)

Type

• Prodotto della ricerca (Classe)
• Articolo in rivista (Classe)

Label

• Detailed analysis of dynamic mechanical properties of TPU nanocomposite: The role of the interfaces (Articolo in rivista) (literal)

Anno

• 2011-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1016/j.eurpolymj.2011.01.005 (literal)

Alternative label

• Marco Aurilia, Filomena Piscitelli, Luigi Sorrentino, Marino Lavorgna, Salvatore Iannace (2011)
  Detailed analysis of dynamic mechanical properties of TPU nanocomposite: The role of the interfaces
  in European Polymer Journal
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Marco Aurilia, Filomena Piscitelli, Luigi Sorrentino, Marino Lavorgna, Salvatore Iannace (literal)

Pagina inizio

• 925 (literal)

Pagina fine

• 936 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 47 (literal)

Rivista

• European Polymer Journal (Rivista)

Note

• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• Istituto per i Materiali Compositi e Biomedici, CNR (literal)

Titolo

• Detailed analysis of dynamic mechanical properties of TPU nanocomposite: The role of the interfaces (literal)

Abstract

• Organo-modified layered silicates (OMLSs) can largely improve mechanical properties of Thermoplastic polyurethanes (TPUs) as well as affect their microdomain morphology. Nanocomposite TPU containing OMLSs were prepared by melt blending at different concentrations. The addition of OMLS has both induced variation in enthalpy of melting of hard and soft phases, and influenced the glass transition temperature of soft domains, as result of the microdomain phase segregation measured by means of fourier transform infrared spectroscopy (FT-IR). Small angle X-ray scattering (SAXS) analysis has shown that the mean distance between hard domains was mostly unaffected by the filler. However, its distribution broadened with the increasing concentration of the OMLSs, resulting in increased extent of the hard domain interface. The storage modulus of TPU nanocomposites incremented with the silicate content, while the dynamic strain scan tests showed pronounced non linear viscoelastic behavior. The analysis of morphological data obtained by SAXS and FT-IR measurements were correlated to thermal and dynamic mechanical properties of TPU samples suggesting a crucial role of the soft domains interface. The storage modulus and loss tangent of TPU nanocomposites were found to increase with the increasing of the interface area of soft domains with both hard domains and OMLS stacks. -------------------------------------------------------------------------------- (literal)

Prodotto di

• Institute for composite and biomedical materials (IMCB) (Istituto)
• Polimeri, compositi e nanostrutture con proprietà funzionali programmate (PM.P02.003.001) (Modulo)

Autore CNR

• SALVATORE IANNACE (Unità di personale interno)
• MARINO LAVORGNA (Unità di personale interno)
• LUIGI SORRENTINO (Persona)

Incoming links:

Prodotto

• Institute for composite and biomedical materials (IMCB) (Istituto)
• Polimeri, compositi e nanostrutture con proprietà funzionali programmate (PM.P02.003.001) (Modulo)

Autore CNR di

• MARINO LAVORGNA (Unità di personale interno)
• SALVATORE IANNACE (Unità di personale interno)
• LUIGI SORRENTINO (Persona)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• European Polymer Journal (Rivista)