http://www.cnr.it/ontology/cnr/individuo/prodotto/ID320032
Homogenous catalytic hydrogenation of bicarbonate with water soluble aryl phosphine ligands (Articolo in rivista)
- Type
- Label
- Homogenous catalytic hydrogenation of bicarbonate with water soluble aryl phosphine ligands (Articolo in rivista) (literal)
- Anno
- 2015-01-01T00:00:00+01:00 (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
- 10.1016/j.ica.2014.10.034 (literal)
- Alternative label
Sordakis, Katerina; Guerriero, Antonella; Bricout, Hervé; Peruzzini, Maurizio; Dyson, Paul J.; Monflier, Éric; Hapiot, Frédéric; Gonsalvi, Luca; Laurenczy, Gábor (2015)
Homogenous catalytic hydrogenation of bicarbonate with water soluble aryl phosphine ligands
in Inorganica Chimica Acta (Testo stamp.); Elsevier, Amsterdam (Paesi Bassi)
(literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
- Sordakis, Katerina; Guerriero, Antonella; Bricout, Hervé; Peruzzini, Maurizio; Dyson, Paul J.; Monflier, Éric; Hapiot, Frédéric; Gonsalvi, Luca; Laurenczy, Gábor (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#altreInformazioni
- invited paper for special issue (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#url
- http://www.scopus.com/record/display.url?eid=2-s2.0-84919684190&origin=inward (literal)
- Rivista
- Note
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
- Ecole Polytechnique Federale de Lausanne; Istituto Di Chimica Dei Composti Organometallici, Sesto Fiorentino; Universite Lille Nord de France (literal)
- Titolo
- Homogenous catalytic hydrogenation of bicarbonate with water soluble aryl phosphine ligands (literal)
- Abstract
- The chemical transformation of CO2 and bicarbonates into useful products becomes increasingly important as the atmospheric CO2 level has reached 400 ppm. Here a small library of sulfonated aryl monophosphines and aryl diphosphines was tested as stabilizing ligands for a ruthenium catalytic precursor in aqueous-phase bicarbonate hydrogenation to formate. The reactions were monitored by high pressure NMR (HPNMR) spectroscopy which also revealed the presence of stable hydride species possibly linked to the superior activity of certain ligands. The different behaviors observed could be related to variations in air stabilities of the ligands. In some cases a pre-activation step of the catalytic precursor was necessary. The effect of such parameters on the stability and recyclability of the catalytic systems is discussed. (literal)
- Editore
- Prodotto di
- Autore CNR
- Insieme di parole chiave
Incoming links:
- Prodotto
- Autore CNR di
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi
- Editore di
- Insieme di parole chiave di