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Characterization of gas phase iron phthalocyanine with X-ray photoelectron and absorption spectroscopies (Articolo in rivista)

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Characterization of gas phase iron phthalocyanine with X-ray photoelectron and absorption spectroscopies (Articolo in rivista) (literal)

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Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

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Bidermane, Ieva/1,2; Lüder, Johann/1; Totani, Roberta/3; Grazioli, Cesare/4,5; De Simone, Monica/4; Coreno, Marcello/5; Kivimäki, Antti/4; Åhlund, John/1; Lozzi, Luca/3; Brena, Barbara/1; Puglia, Carla/1 (2015)
Characterization of gas phase iron phthalocyanine with X-ray photoelectron and absorption spectroscopies
in Physica status solidi. B, Basic research; Wiley-VCH-Verl.., -Weinheim (Germania)
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Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

Bidermane, Ieva/1,2; Lüder, Johann/1; Totani, Roberta/3; Grazioli, Cesare/4,5; De Simone, Monica/4; Coreno, Marcello/5; Kivimäki, Antti/4; Åhlund, John/1; Lozzi, Luca/3; Brena, Barbara/1; Puglia, Carla/1 (literal)

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http://www.scopus.com/record/display.url?eid=2-s2.0-84922571924&origin=inward (literal)

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1 Department of Physics and Astronomy, Uppsala University, 75120 Uppsala, Sweden 2 Institut des Nanosciences de Paris, UPMC Univ. Paris 06, CNRS UMR 7588, 75005, Paris, France 3 Department of Physical and Chemical Sciences, University of L'Aquila, Via Vetoio, 67010 Coppito, L'Aquila, Italy 4 CNR-IOM, Laboratorio TASC, ss. 14 km. 163.5, Basovizza, 34149 Trieste, Italy 5 Department of Chemical and Pharmaceutical Sciences, University of Trieste, 34127 Trieste, Italy 6 CNR-ISM, Basovizza Area Science Park, 34149 Trieste, Italy (literal)

Titolo

Characterization of gas phase iron phthalocyanine with X-ray photoelectron and absorption spectroscopies (literal)

Abstract

Despite the numerous studies dedicated to phthalocyanine molecules adsorbed on surfaces, in monolayer or thin film, very few works have been focused on the characterization of vapors of these molecules. In this article we present the C 1s, N 1s and Fe 2p photoemission results as well as N K-edge X-ray absorption data of iron phthalocyanine (FePc) in gas phase. Presented comparison of X-ray photoelectron spectroscopy and X-ray absorption spectroscopy spectra of FePc films show a great similarity with the gas phase results, confirming the molecular character of thick films. The Fe 2p photoemission spectrum of the gas phase FePc, shown for the first time, can be considered as a fingerprint of the Fe(II) ionic state of the central metal of the iron phthalocyanine. The performed multiplet calculations for describing the Fe 2p XP spectrum indicate 3Eg (a1g2eg3b2g1) state as the most probable ground state for thick film of iron phthalocyanine. (literal)

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