Novel Ziegler/Natta Catalysts Based on Titanium (IV) Complexes with Biscarboxylato Ligands and Organoaluminium Compounds for the Copolymerization of Ethylene with 1-Hexene (Articolo in rivista)

Type

• Articolo in rivista (Classe)
• Prodotto della ricerca (Classe)

Label

• Novel Ziegler/Natta Catalysts Based on Titanium (IV) Complexes with Biscarboxylato Ligands and Organoaluminium Compounds for the Copolymerization of Ethylene with 1-Hexene (Articolo in rivista) (literal)

Anno

• 2007-01-01T00:00:00+01:00 (literal)

Alternative label

• C. Carlini 1, A. D’alessio 1, S. Giaiacopi 1, R. Po 2, M. Pracella 3, A. M. Raspolli 1 Galletti, G. Sbrana (2007)
  Novel Ziegler/Natta Catalysts Based on Titanium (IV) Complexes with Biscarboxylato Ligands and Organoaluminium Compounds for the Copolymerization of Ethylene with 1-Hexene
  in Polymer (Guildford)
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• C. Carlini 1, A. D’alessio 1, S. Giaiacopi 1, R. Po 2, M. Pracella 3, A. M. Raspolli 1 Galletti, G. Sbrana (literal)

Pagina inizio

• 1185 (literal)

Pagina fine

• 1192 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 48 (literal)

Rivista

• Polymer (Rivista)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#note

• cit. 2 (literal)

Note

• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• 1. Dip. Chimica e Chimica Ind.le, Univ. di Pisa, Pisa 2. Istituto Guido Donegani e EniTecnologie, Novara 3. Istituto per i Materiali Compositi e Biomedici, CNR, Pisa (literal)

Titolo

• Novel Ziegler/Natta Catalysts Based on Titanium (IV) Complexes with Biscarboxylato Ligands and Organoaluminium Compounds for the Copolymerization of Ethylene with 1-Hexene (literal)

Abstract

• The co-polymerization of ethylene with 1-hexene has been performed with titanium precursors based on carboxylato ligands in the presence of organoaluminium compounds as activators to afford linear low-density polyethylenes (LLDPEs). The influence of the polymerization parameters was studied with particular reference to the type and amount of catalyst components, solvent, temperature, ethylene pressure, 1-hexene concentration. The chloro-substituted bis-carboxylato titanium complex resulted the most active precursor in the co-polymerization, allowing to obtain copolymers with modulable composition in the 1e5 mol% range of 1-hexene units. The obtained copolymers were characterized by thermal analysis, X-ray diffraction spectroscopy, FTIR and NMR techniques. (literal)

Prodotto di

• Polimeri, compositi e nanostrutture con proprietà funzionali programmate (PM.P02.003.001) (Modulo)
• Institute for composite and biomedical materials (IMCB) (Istituto)

Autore CNR

• MARIANO PRACELLA (Unità di personale interno)

Insieme di parole chiave

• Keywords of "Novel Ziegler/Natta Catalysts Based on Titanium (IV) Complexes with Biscarboxylato Ligands and Organoaluminium Compounds for the Copolymerization of Ethylene with 1-Hexene" (Insieme di parole chiave)

Incoming links:

Autore CNR di

• MARIANO PRACELLA (Unità di personale interno)

Prodotto

• Institute for composite and biomedical materials (IMCB) (Istituto)
• Polimeri, compositi e nanostrutture con proprietà funzionali programmate (PM.P02.003.001) (Modulo)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Polymer (Rivista)

Insieme di parole chiave di

• Keywords of "Novel Ziegler/Natta Catalysts Based on Titanium (IV) Complexes with Biscarboxylato Ligands and Organoaluminium Compounds for the Copolymerization of Ethylene with 1-Hexene" (Insieme di parole chiave)