Polymerization of phenylacetylene and of p-tolyl-acetylene catalyzed by beta-dioxygenato rhodium(I) complexes in homogeneous and heterogeneous phase (Articolo in rivista)

Type

• Prodotto della ricerca (Classe)
• Articolo in rivista (Classe)

Label

• Polymerization of phenylacetylene and of p-tolyl-acetylene catalyzed by beta-dioxygenato rhodium(I) complexes in homogeneous and heterogeneous phase (Articolo in rivista) (literal)

Anno

• 2002-01-01T00:00:00+01:00 (literal)

Alternative label

• 1 Mastrorilli P., 1 Nobile C.F., 1 Rizzuti A., 1 Suranna G.P., 2 Acierno D., 3 Amendola E. (2002)
  Polymerization of phenylacetylene and of p-tolyl-acetylene catalyzed by beta-dioxygenato rhodium(I) complexes in homogeneous and heterogeneous phase
  
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• 1 Mastrorilli P., 1 Nobile C.F., 1 Rizzuti A., 1 Suranna G.P., 2 Acierno D., 3 Amendola E. (literal)

Pagina inizio

• 35 (literal)

Pagina fine

• 42 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 178 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#descrizioneSinteticaDelProdotto

• The paper descibes the synthesis of new polymers obtained by homogeneous and heterogeneous synthesis. The new polymers are potential materials for the production of electronic devices. (literal)

Note

• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• 1 Polytechnic of Bari DIAC 2 University on Naples DIMP 3 CNR IMCB (literal)

Titolo

• Polymerization of phenylacetylene and of p-tolyl-acetylene catalyzed by beta-dioxygenato rhodium(I) complexes in homogeneous and heterogeneous phase (literal)

Abstract

• The catalytic polymn. of phenylacetylene and p-tolyl-acetylene under homogeneous and heterogeneous conditions is described. The catalysts used are either (cod)Rh(AAEMA) [cod: 1,5-cyclooctadiene, AAEMA-: deprotonated form of 2-(acetoacetoxy)ethyl methacrylate] or the supported metal complex obtained by thermal copolymn. of (cod)Rh(AAEMA) with suitable comonomer and cross-linkers. Complexes of general formula (diene)Rh(acac) [diene: 2,5-norbornadiene (nbd) or 1,5-cyclooctadiene (cod)] have also been used for comparison. High yields in poly(aryl-acetylene) are achieved in the homogeneous phase for both substrates using THF as solvent at room temp. even in the absence of any co-catalyst. The use of the supported rhodium(I) catalyst facilitates the polymn. of arylacetylenes yielding, in the case of poly(phenylacetylene) (PPA), a polymer having high stereoregularity and higher mol. wt. respect to that obtained in homogeneous phase. A new correlation between IR data and the cis-percentage of PPA is proposed and discussed (literal)

Prodotto di

• Istituto per i materiali compositi e biomedici (IMCB) (Istituto)
• Polimeri, compositi e nanostrutture con proprietà funzionali programmate (PM.P02.003.001) (Modulo)

Autore CNR

• EUGENIO AMENDOLA (Unità di personale interno)

Insieme di parole chiave

• Keywords of "Polymerization of phenylacetylene and of p-tolyl-acetylene catalyzed by beta-dioxygenato rhodium(I) complexes in homogeneous and heterogeneous phase" (Insieme di parole chiave)

Incoming links:

Prodotto

• Istituto per i materiali compositi e biomedici (IMCB) (Istituto)
• Polimeri, compositi e nanostrutture con proprietà funzionali programmate (PM.P02.003.001) (Modulo)

Autore CNR di

• EUGENIO AMENDOLA (Unità di personale interno)

Insieme di parole chiave di

• Keywords of "Polymerization of phenylacetylene and of p-tolyl-acetylene catalyzed by beta-dioxygenato rhodium(I) complexes in homogeneous and heterogeneous phase" (Insieme di parole chiave)