X-ray structures versus NMR signals in pentacoordinate [PtX2(?2-CH2=CH2)(Me2phen)] (X = Cl, Br, I), complexes. (Articolo in rivista)

Type

• Articolo in rivista (Classe)
• Prodotto della ricerca (Classe)

Label

• X-ray structures versus NMR signals in pentacoordinate [PtX2(?2-CH2=CH2)(Me2phen)] (X = Cl, Br, I), complexes. (Articolo in rivista) (literal)

Anno

• 2015-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1016/j.ica.2015.01.003 (literal)

Alternative label

• Benedetti M. 1, Papadia P. 1, Girelli C. R. 1, De Castro F. 1, Capitelli F. 2, Fanizzi F. P. 1 (2015)
  X-ray structures versus NMR signals in pentacoordinate [PtX2(?2-CH2=CH2)(Me2phen)] (X = Cl, Br, I), complexes.
  in Inorganica Chimica Acta (Testo stamp.)
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Benedetti M. 1, Papadia P. 1, Girelli C. R. 1, De Castro F. 1, Capitelli F. 2, Fanizzi F. P. 1 (literal)

Pagina inizio

• 8 (literal)

Pagina fine

• 13 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 428 (literal)

Rivista

• Inorganica Chimica Acta (Rivista)

Note

• Scopus (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• 1) Università del Salento 2) IC-CNR (literal)

Titolo

• X-ray structures versus NMR signals in pentacoordinate [PtX2(?2-CH2=CH2)(Me2phen)] (X = Cl, Br, I), complexes. (literal)

Abstract

• The single crystal X-ray structure of the pentacoordinate complex [PtBr2(g2-CH2@CH2)(Me2phen)], Me2phen = 2,9-dimethyl-1,10-phenanthroline, is here reported for the first time. Comparison of the complete series of [PtX2(g2-CH2@CH2)(Me2phen)] (X = Cl, Br, I) X-ray structures shows a very low variability of the bond lengths and angles, in the trigonal equatorial plane (where g2-olefin and Me2phen are bound), on varying the coordinated axial halogens. In first approximation, this suggests describing as independents and not interacting the two subsystems constituted by the metal bonds with axial (X-Pt-X) and equatorial ligands (Me2phen-Pt-g2-ethene). This means that the electric charge donated to the metal, by the axial ligands, cannot substantially modify the bonds of the metal with the ligands in the trigonal equatorial plane. The 1H, 13C, 15N and 195Pt NMR chemical shifts variations, studied as a function of the ionic radius of the axial halides are here discussed. The NMR data strongly suggest the existence of electric pseudo-ring currents circulating around the Pt-X axes and modulated by the ionic radius of the coordinated halides. (literal)

Prodotto di

• Institute of Crystallography (IC) (Istituto)
• Sviluppo e Applicazioni di Metodologie Cristallografiche per la soluzione strutturale da cristallo singolo tramite raggi X, elettroni e neutroni (PM.P01.024.002) (Modulo)

Autore CNR

• FRANCESCO CAPITELLI (Unità di personale interno)

Insieme di parole chiave

• Keywords of "X-ray structures versus NMR signals in pentacoordinate [PtX2(?2-CH2=CH2)(Me2phen)] (X = Cl, Br, I), complexes." (Insieme di parole chiave)

Incoming links:

Prodotto

• Institute of Crystallography (IC) (Istituto)
• Sviluppo e Applicazioni di Metodologie Cristallografiche per la soluzione strutturale da cristallo singolo tramite raggi X, elettroni e neutroni (PM.P01.024.002) (Modulo)

Autore CNR di

• FRANCESCO CAPITELLI (Unità di personale interno)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Inorganica Chimica Acta (Rivista)

Insieme di parole chiave di

• Keywords of "X-ray structures versus NMR signals in pentacoordinate [PtX2(?2-CH2=CH2)(Me2phen)] (X = Cl, Br, I), complexes." (Insieme di parole chiave)