New greenish-yellow and yellowish-green emitting glass phosphors: Tb3+/Eu3+ and Ce3+/Tb3+/Eu3+ in zinc phosphate glasses (Articolo in rivista)

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Label
  • New greenish-yellow and yellowish-green emitting glass phosphors: Tb3+/Eu3+ and Ce3+/Tb3+/Eu3+ in zinc phosphate glasses (Articolo in rivista) (literal)
Anno
  • 2013-01-01T00:00:00+01:00 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
  • 10.1016/j.jlumin.2012.10.013 (literal)
Alternative label
  • Caldino, U.; Alvarez, E.; Speghini, A.; Bettinelli, M. (2013)
    New greenish-yellow and yellowish-green emitting glass phosphors: Tb3+/Eu3+ and Ce3+/Tb3+/Eu3+ in zinc phosphate glasses
    in Journal of luminescence
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Caldino, U.; Alvarez, E.; Speghini, A.; Bettinelli, M. (literal)
Pagina inizio
  • 216 (literal)
Pagina fine
  • 220 (literal)
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  • 135 (literal)
Rivista
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#pagineTotali
  • 5 (literal)
Note
  • ISI Web of Science (WOS) (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • Metropolitan Autonomous University - Mexico; Universidad de Sonora; University of Verona; INSTM; IFAC CNR (literal)
Titolo
  • New greenish-yellow and yellowish-green emitting glass phosphors: Tb3+/Eu3+ and Ce3+/Tb3+/Eu3+ in zinc phosphate glasses (literal)
Abstract
  • A spectroscopic investigation of zinc phosphate glasses activated with Eu3+, Tb3+/Eu3+ and Ce3+/Tb3+/Eu3+ ions is performed through photoluminescence spectra and decay time measurements. Greenish-yellow light emission, with x=0.42 and y=0.50 CIE1931 chromaticity coordinates, is obtained in the 5.0% Tb(PO3)(3)-2.0% Eu(PO3)(3) codoped zinc phosphate glass upon Tb3+ excitation at 340 nm. Such greenish-yellow luminescence is generated mainly by the D-5(4) -> F-7(6,5) and D-5(0) -> F-7(1,2) emissions of Tb3+ and Eu3+, respectively, europium being sensitized by terbium through a non-radiative energy transfer. By codoping with 0.1 Ce(PO3)(3) in addition to Tb3+/Eu3+ yellowish-green light emission with CIE1931 chromaticity coordinates, x=0.33 and y=0.48, is achieved through non-radiative energy transfer from Ce3+ to Tb3+ and from Ce3+ via Tb3+ to Eu3+ upon 280 nm excitation (peak emission wavelength of AlGaN-based LEDs). (c) 2012 Elsevier B.V. All rights reserved. (literal)
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