Structure and dynamics of pentacene on SiO2: From monolayer to bulk structure (Articolo in rivista)

Type
Label
  • Structure and dynamics of pentacene on SiO2: From monolayer to bulk structure (Articolo in rivista) (literal)
Anno
  • 2012-01-01T00:00:00+01:00 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
  • 10.1103/PhysRevB.85.195308 (literal)
Alternative label
  • Brillante, Aldo; Bilotti, Ivano; Della Valle, Raffaele Guido; Venuti, Elisabetta; Girlando, Alberto; Masino, Matteo; Liscio, Fabiola; Milita, Silvia; Albonetti, Cristiano; D'angelo, Pasquale; Shehu, Arian; Biscarini, Fabio (2012)
    Structure and dynamics of pentacene on SiO2: From monolayer to bulk structure
    in Physical review. B, Condensed matter and materials physics
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Brillante, Aldo; Bilotti, Ivano; Della Valle, Raffaele Guido; Venuti, Elisabetta; Girlando, Alberto; Masino, Matteo; Liscio, Fabiola; Milita, Silvia; Albonetti, Cristiano; D'angelo, Pasquale; Shehu, Arian; Biscarini, Fabio (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 85 (literal)
Rivista
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  • 9 (literal)
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  • 19 (literal)
Note
  • ISI Web of Science (WOS) (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • Dipartimento Chim Fis & Inorgan; INSTM UdR Bologna; University of Bologna; Dipartimento Chim GIAF; INSTM UdR Parma; University of Parma; Consiglio Nazionale delle Ricerche (CNR); Ist Studio Mat Nanostrutturati (literal)
Titolo
  • Structure and dynamics of pentacene on SiO2: From monolayer to bulk structure (literal)
Abstract
  • We have used confocal micro Raman spectroscopy, atomic force microscopy (AFM), and x-ray diffraction (XRD) to investigate pentacene films obtained by vacuum deposition on SiO2 substrates. These methods allow us to follow the evolution of lattice structure, vibrational dynamics, and crystal morphology during the growth from monolayer, to TF, and, finally, to bulk crystal. The Raman measurements, supported by the AFM and XRD data, indicate that the film morphology depends on the deposition rate. High deposition rates yield two-dimensional nucleation and quasi-layer-by-layer growth of the T-F form only. Low rates yield three-dimensional nucleation and growth, with phase mixing occurring in sufficiently thick films, where the T-F form is accompanied by the \"high-temperature\" bulk phase. Our general findings are consistent with those of previous work. However, the Raman measurements, supported by lattice dynamics calculations, provide additional insight into the nature of the TFs, showing that their characteristic spectra originate from a loss of dynamical correlation between adjacent layers. (literal)
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