Gold Nanowired: A Linear (Au25 )n Polymer from Au25Molecular Clusters (Articolo in rivista)

Type

• Articolo in rivista (Classe)
• Prodotto della ricerca (Classe)

Label

• Gold Nanowired: A Linear (Au25 )n Polymer from Au25Molecular Clusters (Articolo in rivista) (literal)

Anno

• 2014-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1021/nn5031143 (literal)

Alternative label

• De Nardi M.; Antonello S.; Jiang D.-E.; Pan F.; Rissanen K.; Ruzzi M., Venzo A.; Zoleo A.; Maran F. (2014)
  Gold Nanowired: A Linear (Au25 )n Polymer from Au25Molecular Clusters
  in ACS nano (Online); ACS, American chemical society, Washington, DC (Stati Uniti d'America)
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• De Nardi M.; Antonello S.; Jiang D.-E.; Pan F.; Rissanen K.; Ruzzi M., Venzo A.; Zoleo A.; Maran F. (literal)

Pagina inizio

• 8505 (literal)

Pagina fine

• 8512 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#url

• http://pubs.acs.org/doi/abs/10.1021/nn5031143 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 8 (literal)

Rivista

• ACS nano (Rivista)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#pagineTotali

• 8 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroFascicolo

• 8 (literal)

Note

• ISI Web of Science (WOS) (literal)
• Scopu (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• 1,2,6,7,8,9 : Department of Chemistry, University of Padova, Via Marzolo 1, 35131 Padova, Italy / 3 : Department of Chemistry, University of California, Riverside, CA 92521, United States / 4,5 : Department of Chemistry, Nanoscience Center, University of Jyväskylä, P.O. Box 35, 40014 Jyväskylä, Finland / 7 : IENI-CNR C/o Department of Chemistry, University of Padova, Via Marzolo 1, 35131 Padova, Italy (literal)

Titolo

• Gold Nanowired: A Linear (Au25 )n Polymer from Au25Molecular Clusters (literal)

Abstract

• Au25(SR)18 has provided fundamental insights into the properties of clusters protected by monolayers of thiolated ligands (SR). Because of its ultrasmall core, 1 nm, Au25(SR)18 displays molecular behavior. We prepared a Au25 cluster capped by n-butanethiolates (SBu), obtained its structure by single-crystal X-ray crystallography, and studied its properties both experimentally and theoretically. Whereas in solution [Au25 (SBu)18]0 is a paramagnetic molecule, in the crystal it becomes a linear polymer of Au25clusters connectedviasingle Au?Au bonds and stabilized by proper orientation of clusters and interdigitation of ligands. At low temperature, [Au25(SBu)18]0 has a nonmagnetic ground state and can be described as a one-dimensional antiferromagnetic system. These findings provide a breakthrough into the properties and possible solid-state applications of molecular gold nanowires (literal)

Editore

• ACS, American chemical society (Editore)

Prodotto di

• Progettazione molecolare di nanosistemi organizzati (PM.P05.007.003) (Modulo)
• Institute of Condensed Matter Chemistry and Energy Technologies (ICMATE) (Istituto)

Autore CNR

• ALFONSO VENZO (Unità di personale interno)

Insieme di parole chiave

• Parole chiave di "Gold Nanowired: A Linear (Au25 )n Polymer from Au25Molecular Clusters" (Insieme di parole chiave)

Incoming links:

Prodotto

• Institute of Condensed Matter Chemistry and Energy Technologies (ICMATE) (Istituto)
• Progettazione molecolare di nanosistemi organizzati (PM.P05.007.003) (Modulo)

Autore CNR di

• ALFONSO VENZO (Unità di personale interno)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• ACS nano (Rivista)

Editore di

• ACS, American chemical society (Editore)

Insieme di parole chiave di

• Parole chiave di "Gold Nanowired: A Linear (Au25 )n Polymer from Au25Molecular Clusters" (Insieme di parole chiave)