Hydrogen migration in formation of NH(A 3Pi) radicals radicals via superexcited states in photodissociation of isoxazole molecules (Articolo in rivista)

Type

• Articolo in rivista (Classe)
• Prodotto della ricerca (Classe)

Label

• Hydrogen migration in formation of NH(A 3Pi) radicals radicals via superexcited states in photodissociation of isoxazole molecules (Articolo in rivista) (literal)

Anno

• 2014-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1063/1.4891808 (literal)

Alternative label

• Zubek M.; Wasowicz T.J.; Dabkowska I.; Kivimaki A.; Coreno M. (2014)
  Hydrogen migration in formation of NH(A 3Pi) radicals radicals via superexcited states in photodissociation of isoxazole molecules
  in The Journal of chemical physics
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Zubek M.; Wasowicz T.J.; Dabkowska I.; Kivimaki A.; Coreno M. (literal)

Pagina inizio

• 064301 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#url

• http://www.scopus.com/inward/record.url?eid=2-s2.0-84906238875&partnerID=q2rCbXpz (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 141 (literal)

Rivista

• ?The ?Journal of chemical physics (Rivista)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroFascicolo

• 6 (literal)

Note

• Scopu (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• Department of Physics of Electronic Phenomena, Gdansk University of Technology, 80-233 Gdansk, Poland; Department of Chemistry, University of Gdansk, 80-952 Gdansk, Poland; CNR-IOM, Laboratorio TASC, 34149 Trieste, Italy; Gas Phase Beamline at Elettra, Basovizza Area Science Park, 34149 Trieste, Italy; CNR-IMIP, Monterotondo, 00016 Rome, Italy (literal)

Titolo

• Hydrogen migration in formation of NH(A 3Pi) radicals radicals via superexcited states in photodissociation of isoxazole molecules (literal)

Abstract

• Formation of the excited NH(A3?) free radicals in the photodissociation of isoxazole (C3H3NO) molecules has been studied over the 14-22 eV energy range using photon-induced fluorescence spectroscopy. The NH(A3?) is produced through excitation of the isoxazole molecules into higher-lying superexcited states. Observation of the NH radical, which is not a structural unit of the isoxazole molecule, corroborates the hydrogen atom (or proton) migration within the molecule prior to dissociation. The vertical excitation energies of the superexcited states were determined and the dissociation mechanisms of isoxazole are discussed. The density functional and ab initio quantum chemical calculations have been performed to study the mechanism of the NH formation. (literal)

Prodotto di

• Dinamica dei processi atomici e molecolari (MD.P03.026.001) (Modulo)
• Institute of structure of matter (ISM) (Istituto)
• Sistemi a bassa densita' e nanostrutture (MD.P06.016.002) (Modulo)

Autore CNR

• ANTTI EERIK KIVIMAKI (Persona)
• MARCELLO CORENO (Unità di personale interno)

Insieme di parole chiave

• Parole chiave di "Hydrogen migration in formation of NH(A 3Pi) radicals radicals via superexcited states in photodissociation of isoxazole molecules" (Insieme di parole chiave)

Incoming links:

Autore CNR di

• MARCELLO CORENO (Unità di personale interno)
• ANTTI EERIK KIVIMAKI (Persona)

Prodotto

• Institute of structure of matter (ISM) (Istituto)
• Dinamica dei processi atomici e molecolari (MD.P03.026.001) (Modulo)
• Sistemi a bassa densita' e nanostrutture (MD.P06.016.002) (Modulo)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• ?The ?Journal of chemical physics (Rivista)

Insieme di parole chiave di

• Parole chiave di "Hydrogen migration in formation of NH(A 3Pi) radicals radicals via superexcited states in photodissociation of isoxazole molecules" (Insieme di parole chiave)