http://www.cnr.it/ontology/cnr/individuo/prodotto/ID300538
Crystal Size, Morphology, and Growth Mechanism in Bio-Inspired Apatite Nanocrystals (Articolo in rivista)
- Type
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- Crystal Size, Morphology, and Growth Mechanism in Bio-Inspired Apatite Nanocrystals (Articolo in rivista) (literal)
- Anno
- 2014-01-01T00:00:00+01:00 (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
- 10.1002/adfm.201302075 (literal)
- Alternative label
Manuel Delgado-Lopez, Jose; Frison, Ruggero; Cervellino, Antonio; Gomez-Morales, Jaime; Guagliardi, Antonietta; Masciocchi, Norberto (2014)
Crystal Size, Morphology, and Growth Mechanism in Bio-Inspired Apatite Nanocrystals
in Advanced functional materials (Print); WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim (Germania)
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- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
- Manuel Delgado-Lopez, Jose; Frison, Ruggero; Cervellino, Antonio; Gomez-Morales, Jaime; Guagliardi, Antonietta; Masciocchi, Norberto (literal)
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- http://onlinelibrary.wiley.com/journal/10.1002/(ISSN)1616-3028 (literal)
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- ISI Web of Science (WOS) (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
- IACT CSIC UGR; Consiglio Nazionale delle Ricerche (CNR); To Sca Lab; Paul Scherrer Institute; University of Insubria; University of Insubria (literal)
- Titolo
- Crystal Size, Morphology, and Growth Mechanism in Bio-Inspired Apatite Nanocrystals (literal)
- Abstract
- Bio-inspired apatite nanoparticles precipitated in the presence of citrate ions at increasing maturation times are characterized in terms of structure, size, morphology, and composition through advanced X-ray total scattering techniques. The origin of the platy crystal morphology, breaking the hexagonal symmetry, and the role ofcitrate ions is explored. By cross-coupling the size and shape information of crystal domains with those obtained by atomic force microscopy on multidomain nanoparticles, a plausible mechanism underlying the amorphous-to-crystal transformation is reconstructed. In the present study, citrate plays the distinct roles of inducing the platy morphology of the amorphous precursor and controlling the thickness of the Ca-deficient apatite nanocrystals. These findings can open new scenarios also in bone mineralization, where citrate might have a broader role to play than has been thought to date. (literal)
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