A mechanistic assessment of the wet air oxidation activity of MnCeOx catalyst toward toxic and refractory organic pollutants (Articolo in rivista)

Type

• Articolo in rivista (Classe)
• Prodotto della ricerca (Classe)

Label

• A mechanistic assessment of the wet air oxidation activity of MnCeOx catalyst toward toxic and refractory organic pollutants (Articolo in rivista) (literal)

Anno

• 2014-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1016/j.apcatb.2013.07.025 (literal)

Alternative label

• Arena, Francesco; Italiano, Cristina; Ferrante, Giovanni Drago; Trunfio, Giuseppe; Spadaro, Lorenzo (2014)
  A mechanistic assessment of the wet air oxidation activity of MnCeOx catalyst toward toxic and refractory organic pollutants
  in Applied catalysis. B, Environmental (Print)
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Arena, Francesco; Italiano, Cristina; Ferrante, Giovanni Drago; Trunfio, Giuseppe; Spadaro, Lorenzo (literal)

Pagina inizio

• 292 (literal)

Pagina fine

• 299 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 144 (literal)

Rivista

• Applied catalysis. B, Environmental (Rivista)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#pagineTotali

• 8 (literal)

Note

• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• University of Messina; Ist CNR ITAE Nicola Giordano (literal)

Titolo

• A mechanistic assessment of the wet air oxidation activity of MnCeOx catalyst toward toxic and refractory organic pollutants (literal)

Abstract

• The reactivity pattern of a model MnCeOx catalyst (Mn-at:Ce-at, 1) in the wet air oxidation (CWAO) of toxic (phenol) and refractory (acetic, oxalic and formic acids) organic pollutants has been probed, using a stirred batch reactor with continuous oxygen feeding (Po-2, 0.9 MPa). In the range of 110-150 degrees C the MnCeOx catalyst (w(cat)/w(sub), 6) shows high abatement and mineralization efficiency toward all the substrates. Parallel trends of substrate and total organic carbon (TOC) conversion prove that adsorption is the primary reaction step, while slower mineralization rates signal that surface oxidation is rate determining step (r.d.s.). Activity data in the pH range of 3-10 and straight relationships between conversion and dissociation constant (K-a) signal that acids adsorption is driven by electrostatic interactions with acid sites (E-Ads approximate to 80 kJ/mol), while a low energetic barrier (E-Ads approximate to 16 kJ/mol) discloses the physical nature of phenol adsorption. A kinetic analysis of conversion-selectivity data, based on a dual-site Langmuir-Hinshelwood (L-H) mechanism, sheds light into the CWAO pattern of MnCeOx catalyst toward different classes of organic pollutants. (C) 2013 Elsevier B.V. All rights reserved. (literal)

Prodotto di

• Institute for advanced energy technologies \"Nicola Giordano\" (ITAE) (Istituto)

Autore CNR

• CRISTINA ITALIANO (Persona)
• LORENZO SPADARO (Unità di personale interno)

Insieme di parole chiave

• Keywords of "A mechanistic assessment of the wet air oxidation activity of MnCeOx catalyst toward toxic and refractory organic pollutants" (Insieme di parole chiave)

Incoming links:

Autore CNR di

• LORENZO SPADARO (Unità di personale interno)
• CRISTINA ITALIANO (Persona)

Prodotto

• Institute for advanced energy technologies \"Nicola Giordano\" (ITAE) (Istituto)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Applied catalysis. B, Environmental (Rivista)

Insieme di parole chiave di

• Keywords of "A mechanistic assessment of the wet air oxidation activity of MnCeOx catalyst toward toxic and refractory organic pollutants" (Insieme di parole chiave)