New SIMS procedures for the characterization of a complex silicate matrix, Na3(REE,Th,Ca,U)Si6O15 × 2.5H2O (Sazhinite), and comparison with EMPA and SREF results. (Articolo in rivista)

Type

• Prodotto della ricerca (Classe)
• Articolo in rivista (Classe)

Label

• New SIMS procedures for the characterization of a complex silicate matrix, Na3(REE,Th,Ca,U)Si6O15 × 2.5H2O (Sazhinite), and comparison with EMPA and SREF results. (Articolo in rivista) (literal)

Anno

• 2004-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1007/s00604-003-0143-9 (literal)

Alternative label

• Ottolini L.; Cámara F.; Devouard B. (2004)
  New SIMS procedures for the characterization of a complex silicate matrix, Na3(REE,Th,Ca,U)Si6O15 × 2.5H2O (Sazhinite), and comparison with EMPA and SREF results.
  in Mikrochimica acta (1966, Internet); SPRINGER-VERLAG, WIEN (Austria)
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Ottolini L.; Cámara F.; Devouard B. (literal)

Pagina inizio

• 139 (literal)

Pagina fine

• 146 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 145 (literal)

Rivista

• Mikrochimica acta (Rivista)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroFascicolo

• 1-4 (literal)

Note

• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• Ottolini L. 1); Cámara F. 1); Devouard B. 2). 1) CNR, Ist Geosci & Georisorse, Sez Pavia, I-27100 Pavia, Italy 2) Univ Clermont Ferrand, CNRS,UMR 6524, OPGC, Lab Magmas & Volcans, F-63038 Clermont Ferrand, France (literal)

Titolo

• New SIMS procedures for the characterization of a complex silicate matrix, Na3(REE,Th,Ca,U)Si6O15 × 2.5H2O (Sazhinite), and comparison with EMPA and SREF results. (literal)

Abstract

• Analytical methods based on secondary ion mass spectrometry were developed for the characterisation of a complex layered silicate REE-mineral, named sazhinite, for which a number of issues are still open regarding its chemistry and structure. Such procedures involved the analysis and quantification of light, volatile, alkaline, medium-Z, rare earth and actinide elements. The accuracy of the SIMS data is within the assigned precision of the concentration values assumed as reference in the calibration standards employed. REE and actinide data yield a good agreement in terms of calculated site scattering at the M site: 58.42 electrons per formula unit (epfu) vs. 60.39epfu obtained by Single Crystal Structure-Refinement (SREF). Accuracy is estimated on the order of 5% rel. for H, Li, Be and B, and 10% rel. for F. Na analysis was crucial to solve the open questions about the structure, and excellent agreement was obtained by comparing data from SIMS (REE, Y, actinides, Na)+EMPA (SiO2, CaO, SO3 and K2O) with information derived from SREF: site scattering of the M site+Na sites=92.56epfu calculated from chemical data, against 91.95epfu from SREF. Such procedures can be easily extended to the analysis of variously complex, silicate REE-minerals. (literal)

Editore

• SPRINGER-VERLAG (Editore)

Prodotto di

• Metodologie integrate per la conoscenza di processi e materiali geologici e del loro impatto sull'uomo e l'ambiente (TA.P04.014.002) (Modulo)
• Istituto di geoscienze e georisorse (IGG) (Istituto)

Autore CNR

• LUISA OTTOLINI (Persona)
• FERNANDO CAMARA ARTIGAS (Persona)

Insieme di parole chiave

• Parole chiave di "New SIMS procedures for the characterization of a complex silicate matrix, Na3(REE,Th,Ca,U)Si6O15 × 2.5H2O (Sazhinite), and comparison with EMPA and SREF results." (Insieme di parole chiave)

Incoming links:

Autore CNR di

• FERNANDO CAMARA ARTIGAS (Persona)
• LUISA OTTOLINI (Persona)

Prodotto

• Istituto di geoscienze e georisorse (IGG) (Istituto)
• Metodologie integrate per la conoscenza di processi e materiali geologici e del loro impatto sull'uomo e l'ambiente (TA.P04.014.002) (Modulo)

Editore di

• SPRINGER-VERLAG (Editore)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Mikrochimica acta (Rivista)

Insieme di parole chiave di

• Parole chiave di "New SIMS procedures for the characterization of a complex silicate matrix, Na3(REE,Th,Ca,U)Si6O15 × 2.5H2O (Sazhinite), and comparison with EMPA and SREF results." (Insieme di parole chiave)