http://www.cnr.it/ontology/cnr/individuo/prodotto/ID292842
Effects of particle size distribution and starting phase composition in Na-feldspar/kaolinite system at high temperature (Articolo in rivista)
- Type
- Label
- Effects of particle size distribution and starting phase composition in Na-feldspar/kaolinite system at high temperature (Articolo in rivista) (literal)
- Anno
- 2015-01-01T00:00:00+01:00 (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
- 10.1016/j.jeurceramsoc.2014.10.035 (literal)
- Alternative label
Diella, Valeria
Adamo, Ilaria
Pagliari, Lucia
Pavese, Alessandro
Francescon, Fernando (2015)
Effects of particle size distribution and starting phase composition in Na-feldspar/kaolinite system at high temperature
in Journal of the European Ceramic Society
(literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
- Diella, Valeria
Adamo, Ilaria
Pagliari, Lucia
Pavese, Alessandro
Francescon, Fernando (literal)
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- National Research Council, IDPA, Section of Milano
Department of Earth Sciences \"Ardito Desio\", University of Milan
Department of Earth Sciences \"Ardito Desio\", University of Milan
Department of Earth Sciences \"Ardito Desio\", University of Milan
Ideal Standard International, C.O.E., Ceramic Process Technology, Via Cavassico Inferiore 160, I-32026 Trichiana, BL, Italy (literal)
- Titolo
- Effects of particle size distribution and starting phase composition in Na-feldspar/kaolinite system at high temperature (literal)
- Abstract
- Mullite-glass Gibbs energy of formation (?Geff), micro-texture and phase composition
evolution are investigated in the Na-feldspar (F) and kaolinite (K) system, over the 1240-1320
°C interval, as a function of the starting F/K ratio by weight and particle size distribution of F
(
), using scanning electron microscopy, X-ray diffraction and thermodynamic modeling.
Electron microscopy images show that size and aspect ratio of primary and secondary mullite
have their largest figures for the smallest and, in general, monotonically increase upon
firing temperature. ?Geff has been modeled by a()×(F/K)2+b()×F/K+g() (a, b and
? are linear functions of ). The parameters of such a function have been determined by
fitting it to the experimental ?Geffs, inferred from quantitative phase analysis of X-ray
diffraction patterns. Note that we used average ?Geff-values over the T-range explored
because of the modest dependence on temperature shown. We have gathered that (i) F/K
affects energetics and mullite content more markedly than does, and (ii) the mullite
formation is energetically favored by decreasing F/K and increasing . (literal)
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