Effects of particle size distribution and starting phase composition in Na-feldspar/kaolinite system at high temperature (Articolo in rivista)

Type
Label
  • Effects of particle size distribution and starting phase composition in Na-feldspar/kaolinite system at high temperature (Articolo in rivista) (literal)
Anno
  • 2015-01-01T00:00:00+01:00 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
  • 10.1016/j.jeurceramsoc.2014.10.035 (literal)
Alternative label
  • Diella, Valeria Adamo, Ilaria Pagliari, Lucia Pavese, Alessandro Francescon, Fernando (2015)
    Effects of particle size distribution and starting phase composition in Na-feldspar/kaolinite system at high temperature
    in Journal of the European Ceramic Society
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Diella, Valeria Adamo, Ilaria Pagliari, Lucia Pavese, Alessandro Francescon, Fernando (literal)
Pagina inizio
  • 1327 (literal)
Pagina fine
  • 1335 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 35 (literal)
Rivista
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#pagineTotali
  • 9 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • National Research Council, IDPA, Section of Milano Department of Earth Sciences \"Ardito Desio\", University of Milan Department of Earth Sciences \"Ardito Desio\", University of Milan Department of Earth Sciences \"Ardito Desio\", University of Milan Ideal Standard International, C.O.E., Ceramic Process Technology, Via Cavassico Inferiore 160, I-32026 Trichiana, BL, Italy (literal)
Titolo
  • Effects of particle size distribution and starting phase composition in Na-feldspar/kaolinite system at high temperature (literal)
Abstract
  • Mullite-glass Gibbs energy of formation (?Geff), micro-texture and phase composition evolution are investigated in the Na-feldspar (F) and kaolinite (K) system, over the 1240-1320 °C interval, as a function of the starting F/K ratio by weight and particle size distribution of F (), using scanning electron microscopy, X-ray diffraction and thermodynamic modeling. Electron microscopy images show that size and aspect ratio of primary and secondary mullite have their largest figures for the smallest and, in general, monotonically increase upon firing temperature. ?Geff has been modeled by a()×(F/K)2+b()×F/K+g() (a, b and ? are linear functions of ). The parameters of such a function have been determined by fitting it to the experimental ?Geffs, inferred from quantitative phase analysis of X-ray diffraction patterns. Note that we used average ?Geff-values over the T-range explored because of the modest dependence on temperature shown. We have gathered that (i) F/K affects energetics and mullite content more markedly than does, and (ii) the mullite formation is energetically favored by decreasing F/K and increasing . (literal)
Prodotto di
Autore CNR
Insieme di parole chiave

Incoming links:


Prodotto
Autore CNR di
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi
Insieme di parole chiave di
data.CNR.it