http://www.cnr.it/ontology/cnr/individuo/prodotto/ID292729
Role of Interfacial Energy I (Articolo in rivista)
- Type
- Label
- Role of Interfacial Energy I (Articolo in rivista) (literal)
- Anno
- 2013-01-01T00:00:00+01:00 (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
- 10.1021/jp3124956 (literal)
- Alternative label
Pin, Sonia; Suardelli, Marco; D'Acapito, Francesco; Spinolo, Giorgio; Zema, Michele; Tarantino, Serena C.; Ghigna, Paolo (2013)
Role of Interfacial Energy I
in Journal of physical chemistry. C
(literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
- Pin, Sonia; Suardelli, Marco; D'Acapito, Francesco; Spinolo, Giorgio; Zema, Michele; Tarantino, Serena C.; Ghigna, Paolo (literal)
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- Note
- ISI Web of Science (WOS) (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
- Paul Scherrer Institute; University of Pavia; cnr-iom (literal)
- Titolo
- Role of Interfacial Energy I (literal)
- Abstract
- The initial steps of the reaction between ZnO and Al2O3 have been investigated with X-ray diffraction, atomic force microscopy, and X-ray absorption spectroscopy at the Zn-K edge starting from 45 nm thick zincite films deposited onto (110)- and (102)-oriented sapphire single crystals. The formation of nonequilibrium phase(s) has been detected for both orientations. For the (001)(zincite) parallel to (110)(sapphire) interface, the rate-determining step is the motion of the interface(s); the growth of the spinel layer is linear with time, with a rate constant k = 1.1(2) x 10(-9) cms(-1) at 1000 degrees C. At the (110)(zincite) parallel to (012)(sapphire) interface, the reaction shows dumped oscillations. The results are discussed along with a comparison with previous results on thinner films to clarify the role of interfacial free energy and crystallographic orientation. (literal)
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