http://www.cnr.it/ontology/cnr/individuo/prodotto/ID292693
EXAFS study of Er,Yb doped hollow and dense SiO2microspheres (Articolo in rivista)
- Type
- Label
- EXAFS study of Er,Yb doped hollow and dense SiO2microspheres (Articolo in rivista) (literal)
- Anno
- 2014-01-01T00:00:00+01:00 (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
- 10.1016/j.jnoncrysol.2014.06.004 (literal)
- Alternative label
L.M. Fortes, M.C. Gonçalves,J.C. Pereira,F.D'Acapito (2014)
EXAFS study of Er,Yb doped hollow and dense SiO2microspheres
in Journal of non-crystalline solids
(literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
- L.M. Fortes, M.C. Gonçalves,J.C. Pereira,F.D'Acapito (literal)
- Pagina inizio
- Pagina fine
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
- Rivista
- Note
- ISI Web of Science (WOS) (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
- Istituto Superior Tecnico, Lisboa
CNR-IOM (literal)
- Titolo
- EXAFS study of Er,Yb doped hollow and dense SiO2microspheres (literal)
- Abstract
- Hollow and dense SiO2microspheres doped with Er,Yb were characterized by extended X-ray absorptionfine structure (EXAFS) on the Er,Yb LIIIedges and photoluminescence (PL)measurements. The samples were synthe-sizedby the sol-gelmethod andin situEr,Ybdoped, by introducingfluoride compounds (ErF3,YbF3) in the sol. Er, Yb doped transparent glass-ceramic, formed by NaYF4nanocrystals dispersed in SiO2matrix, was taken as the reference. The EXAFS results illustrate the Er,Yb local environment in all studied SiO2matrices: in hollow-microspheres, crystalline Er,Ybfluoride was formed while in dense-microspheres, crystalline Er,Yb oxide developed. PL measurements of the Er 3+ emission at 1.54?m were performed, on hollow and dense SiO2microspheres, for different Er 3+ /Yb 3+ ratios, ranging from 1:3 to 1:10 mol%. Upconversion was observed inall samples, ordered by efficiency for the studied Er,Yb environments as: glass-ceramic (NaYF4environment)>>hollow SiO2micro-spheres (Er,Ybfluoride crystalline environment)Ndense SiO2microspheres (Er,Yb oxide crystalline environ-ment). X-ray excited optical luminescence (XEOL) confirmed the Er green upconversion results (literal)
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