http://www.cnr.it/ontology/cnr/individuo/prodotto/ID289141
PtRu nanoparticles deposited by the sulfite complex method on highly porous carbon xerogels: Effect of the thermal treatment (Articolo in rivista)
- Type
- Label
- PtRu nanoparticles deposited by the sulfite complex method on highly porous carbon xerogels: Effect of the thermal treatment (Articolo in rivista) (literal)
- Anno
- 2013-01-01T00:00:00+01:00 (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
- 10.3390/catal3030744 (literal)
- Alternative label
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
- Alegre C.; Sebastian D.; Galvez M.E.; Moliner R.; Stassi A.; Arico A.S.; Lazaro M.J.; Baglio V. (literal)
- Pagina inizio
- Pagina fine
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- http://www.scopus.com/inward/record.url?eid=2-s2.0-84906887616&partnerID=q2rCbXpz (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
- Rivista
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- Note
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- Institute for Advanced Energy Technologies 'Nicola Giordano', CNR-Consiglio Nazionale della Ricerca, Vía Salita Santa Lucía sopra Contesse, 5, 98126 Messina, Italy; Swiss Federal Institute of Technology, ETH Zurich, Sonneggstrasse 3, 8092 Zürich, Switzerland; Institute of Carbochemistry, CSIC-Spanish National Research Council, C/. Miguel Luesma Castán, 4, 50018 Zaragoza, Spain (literal)
- Titolo
- PtRu nanoparticles deposited by the sulfite complex method on highly porous carbon xerogels: Effect of the thermal treatment (literal)
- Abstract
- Highly porous carbon xerogels (CXGs) were synthesized to be used as support
for PtRu nanoparticles. Metal particles were deposited on CXGs by means of the sulfite
complex method for the first time. Catalysts so-obtained were submitted to thermal
treatment in H2, at different temperatures, in order to increase the particle size and thus the
intrinsic activity. Physico-chemical characterizations included N2 physisorption, X-Ray
diffraction, X-ray photoelectron spectroscopy and transmission electron microscopy.
Highly dispersed alloyed PtRu particles were obtained, with crystal sizes ranging from 1.6
to 2.0 nm. PtRu-catalysts were tested in half-cell for the methanol oxidation reaction
(MOR). The resulting thermal treatment was effective in increasing both particle size and
catalytic activity toward MOR. (literal)
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