A vibrational spectroscopic and principal component analysis of triarylmethane dyes by comparative laboratory and portable instrumentation (Articolo in rivista)

Type
Label
  • A vibrational spectroscopic and principal component analysis of triarylmethane dyes by comparative laboratory and portable instrumentation (Articolo in rivista) (literal)
Anno
  • 2014-01-01T00:00:00+01:00 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
  • 10.1016/j.saa.2013.10.069 (literal)
Alternative label
  • Doherty, Brenda J S; Vagnini, Manuela; Dufourmantelle, K.; Sgamellotti, Antonio; Brunetti, Brunetto Giovanni; Miliani, Costanza (2014)
    A vibrational spectroscopic and principal component analysis of triarylmethane dyes by comparative laboratory and portable instrumentation
    in Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy (Print)
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Doherty, Brenda J S; Vagnini, Manuela; Dufourmantelle, K.; Sgamellotti, Antonio; Brunetti, Brunetto Giovanni; Miliani, Costanza (literal)
Pagina inizio
  • 292 (literal)
Pagina fine
  • 305 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#url
  • http://www.scopus.com/record/display.url?eid=2-s2.0-84887571752&origin=inward (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 121 (literal)
Rivista
Note
  • Scopu (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • Universita degli Studi di Perugia; Associazione Laboratorio di Diagnostica di Spoleto; Parks Canada (literal)
Titolo
  • A vibrational spectroscopic and principal component analysis of triarylmethane dyes by comparative laboratory and portable instrumentation (literal)
Abstract
  • This contribution examines the utility of vibrational spectroscopy by bench and portable Raman/surface enhanced Raman and infrared methods for the investigation of ten early triarlymethane dye powder references and dye solutions applied on paper. The complementary information afforded by the techniques is shown to play a key role in the identification of specific spectral marker ranges to distiguish early synthetic dyes of art-historical interest through the elaboration of an in-house database of modern organic dyes. Chemometric analysis has permitted a separation of data by the discrimination of di-phenyl-naphthalenes and triphenylmethanes (di-amino and tri-amino derivatives). This work serves as a prelude to the validation of a non-invasive working method for in situ characterization of these synthetic dyes through a careful comparison of respective strengths and limitations of each portable technique.© 2013 Elsevier B.V. All rights reserved. (literal)
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