Screening of N,N-bidentate and N,N,Ntridentate pyridine-based ligands in the catalytic allylic oxidation of cyclic olefins (Articolo in rivista)

Type

• Prodotto della ricerca (Classe)
• Articolo in rivista (Classe)

Label

• Screening of N,N-bidentate and N,N,Ntridentate pyridine-based ligands in the catalytic allylic oxidation of cyclic olefins (Articolo in rivista) (literal)

Anno

• 2014-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1002/aoc.3222 (literal)

Alternative label

• Maurizio Solinas, Barbara Sechi, Giorgio Chelucci (2014)
  Screening of N,N-bidentate and N,N,Ntridentate pyridine-based ligands in the catalytic allylic oxidation of cyclic olefins
  in Applied organometallic chemistry (Online)
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Maurizio Solinas, Barbara Sechi, Giorgio Chelucci (literal)

Pagina inizio

• 831 (literal)

Pagina fine

• 834 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 28 (literal)

Rivista

• Applied organometallic chemistry (Rivista)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#pagineTotali

• 4 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• CNR, Istituto di Chimica Biomolecolare UOS Sassari, Traversa La Crucca 3, 07100, Sassari, Italy; Dipartimento di Agraria, Università di Sassari, Viale Italia 39, 07100, Sassari, Italy (literal)

Titolo

• Screening of N,N-bidentate and N,N,Ntridentate pyridine-based ligands in the catalytic allylic oxidation of cyclic olefins (literal)

Abstract

• A variety of chiral N,N-bidentate and N,N,N-tridentate ligands based on the pyridine framework, namely C2-symmetric dipyridylmethane and terpyridine, N-(p-toluensulfinyl)iminopyridines and two kinds of iminopyridines, has been assessed in the asymmetric copper(I)-catalysed allylic oxidation of cyclic olefins. Catalytic activity and enantioselectivity were found to be highly dependent upon the framework of the ligands, which afforded cycloalkenyl benzoates in low to moderate yields and enantioselectivities. The best yields (up to 70%) and enantioselectivities (up to 53% enantiomeric excess) were obtained with an iminopyridine based on camphane and quinoline skeletons. (literal)

Prodotto di

• Institute of biomolecular chemistry (ICB) (Istituto)

Autore CNR

• BARBARA SECHI (Persona)
• MAURIZIO SOLINAS (Unità di personale interno)

Incoming links:

Prodotto

• Institute of biomolecular chemistry (ICB) (Istituto)

Autore CNR di

• BARBARA SECHI (Persona)
• MAURIZIO SOLINAS (Unità di personale interno)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Applied organometallic chemistry (Rivista)