Understanding the Electronic Structure of IrO2 Using Hard-X-ray Photoelectron Spectroscopy and Density-Functional Theory (Articolo in rivista)

Type

• Prodotto della ricerca (Classe)
• Articolo in rivista (Classe)

Label

• Understanding the Electronic Structure of IrO2 Using Hard-X-ray Photoelectron Spectroscopy and Density-Functional Theory (Articolo in rivista) (literal)

Anno

• 2014-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1103/PhysRevLett.112.117601 (literal)

Alternative label

• Kahk, J. M. and Poll, C. G. and Oropeza, F. E. and Ablett, J. M. and Geolin, D. and Rueff, J-P. and Agrestini, S. and Utsumi, Y. and Tsuei, K. D. and Liao, Y. F. and Borgatti, F. and Panaccione, G. and Regoutz, A. and Egdell, R. G. and Morgan, B. J. and Scanlon, D. O. and Payne, D. J. (2014)
  Understanding the Electronic Structure of IrO2 Using Hard-X-ray Photoelectron Spectroscopy and Density-Functional Theory
  in Physical review letters (Print)
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Kahk, J. M. and Poll, C. G. and Oropeza, F. E. and Ablett, J. M. and Geolin, D. and Rueff, J-P. and Agrestini, S. and Utsumi, Y. and Tsuei, K. D. and Liao, Y. F. and Borgatti, F. and Panaccione, G. and Regoutz, A. and Egdell, R. G. and Morgan, B. J. and Scanlon, D. O. and Payne, D. J. (literal)

Pagina inizio

• 117601-1 (literal)

Pagina fine

• 117601-6 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 112 (literal)

Rivista

• Physical review letters (Rivista)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#pagineTotali

• 6 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroFascicolo

• 11 (literal)

Note

• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• Kahk, JM (Reprint Author), Univ London Imperial Coll Sci Technol & Med, Dept Mat, London SW7 2AZ, England. Kahk, J. M.; Poll, C. G.; Oropeza, F. E.; Payne, D. J., Univ London Imperial Coll Sci Technol & Med, Dept Mat, London SW7 2AZ, England. Ablett, J. M.; Geolin, D.; Rueff, J-P., Synchrotron SOLEIL, F-91192 Gif Sur Yvette, France. Utsumi, Y., Max Planck Inst Chem Phys Solids, D-01187 Dresden, Germany. Tsuei, K. D.; Liao, Y. F., Natl Synchrotron Radiat Res Ctr, Hsinchu 30077, Taiwan. Borgatti, F., CNR ISMN, I-40129 Bologna, Italy. Panaccione, G., IOM CNR, Lab TASC, I-34149 Trieste, Italy. Regoutz, A.; Egdell, R. G., Univ Oxford, Dept Chem, Chem Res Lab, Oxford OX1 3TA, England. Morgan, B. J., Univ Oxford, Dept Mat, Oxford OX1 3PH, England. Scanlon, D. O., UCL, Dept Chem, London WC1H 0AJ, England. Scanlon, D. O., Diamond Light Source Ltd, Harwell OX11 0DE, Berks, England. (literal)

Titolo

• Understanding the Electronic Structure of IrO2 Using Hard-X-ray Photoelectron Spectroscopy and Density-Functional Theory (literal)

Abstract

• The electronic structure of IrO2 has been investigated using hard x-ray photoelectron spectroscopy and density-functional theory. Excellent agreement is observed between theory and experiment. We show that the electronic structure of IrO2 involves crystal field splitting of the iridium 5d orbitals in a distorted octahedral field. The behavior of IrO2 closely follows the theoretical predictions of Goodenough for conductive rutile-structured oxides [J. B. Goodenough, J. Solid State Chem. 3, 490 (1971)]. Strong satellites associated with the core lines are ascribed to final state screening effects. A simple plasmon model for the satellites applicable to many other metallic oxides appears to be not valid for IrO2. (literal)

Prodotto di

• Nanostrutture Magnetiche per la Spintronica e la Nanomedicina (PM.P04.006.002) (Modulo)
• Istituto per lo studio dei materiali nanostrutturati (ISMN) (Istituto)

Autore CNR

• FRANCESCO BORGATTI (Unità di personale interno)
• GIANCARLO PANACCIONE (Unità di personale interno)

Insieme di parole chiave

• Parole chiave di "Understanding the Electronic Structure of IrO2 Using Hard-X-ray Photoelectron Spectroscopy and Density-Functional Theory" (Insieme di parole chiave)

Incoming links:

Autore CNR di

• GIANCARLO PANACCIONE (Unità di personale interno)
• FRANCESCO BORGATTI (Unità di personale interno)

Prodotto

• Istituto per lo studio dei materiali nanostrutturati (ISMN) (Istituto)
• Nanostrutture Magnetiche per la Spintronica e la Nanomedicina (PM.P04.006.002) (Modulo)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Physical review letters (Rivista)

Insieme di parole chiave di

• Parole chiave di "Understanding the Electronic Structure of IrO2 Using Hard-X-ray Photoelectron Spectroscopy and Density-Functional Theory" (Insieme di parole chiave)