Confining Phosphanes Derived from Cyclodextrins for Efficient Regio-and Enantioselective Hydroformylation (Articolo in rivista)

Type

• Prodotto della ricerca (Classe)
• Articolo in rivista (Classe)

Label

• Confining Phosphanes Derived from Cyclodextrins for Efficient Regio-and Enantioselective Hydroformylation (Articolo in rivista) (literal)

Anno

• 2014-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1002/anie.201311291 (literal)

Alternative label

• Jouffroy, Matthieu; Gramage-Doria, Rafael; Armspach, Dominique; Semeril, David; Oberhauser, Werner; Matt, Dominique; Toupet, Loic; (2014)
  Confining Phosphanes Derived from Cyclodextrins for Efficient Regio-and Enantioselective Hydroformylation
  in Angewandte Chemie (Int. ed., Print)
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Jouffroy, Matthieu; Gramage-Doria, Rafael; Armspach, Dominique; Semeril, David; Oberhauser, Werner; Matt, Dominique; Toupet, Loic; (literal)

Pagina inizio

• 3937 (literal)

Pagina fine

• 3940 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 53 (literal)

Rivista

• Angewandte Chemie (Rivista)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#pagineTotali

• 4 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• CNRS, Università di Strassburgo ICCOM-CNR (literal)

Titolo

• Confining Phosphanes Derived from Cyclodextrins for Efficient Regio-and Enantioselective Hydroformylation (literal)

Abstract

• Two confining phosphane ligands derived from either a- or b-cyclodextrin produce singly PIII-ligated metal complexes with unusual coordination spheres. High-pressure NMR studies have revealed that rhodium hydride complexes of the same type are also formed under hydroformylation conditions. This unique feature strongly favors the formation of the branched aldehyde at the expense of the linear one with high enantioselectivity in the rhodium-catalyzed hydroformylation of styrene (literal)

Prodotto di

• Institute of chemistry of organometallic compounds (ICCOM) (Istituto)

Autore CNR

• WERNER OBERHAUSER (Unità di personale interno)

Insieme di parole chiave

• Keywords of "Confining Phosphanes Derived from Cyclodextrins for Efficient Regio-and Enantioselective Hydroformylation" (Insieme di parole chiave)

Incoming links:

Prodotto

• Institute of chemistry of organometallic compounds (ICCOM) (Istituto)

Autore CNR di

• WERNER OBERHAUSER (Unità di personale interno)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Angewandte Chemie (Rivista)

Insieme di parole chiave di

• Keywords of "Confining Phosphanes Derived from Cyclodextrins for Efficient Regio-and Enantioselective Hydroformylation" (Insieme di parole chiave)