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Effect of thermal treatments on sputtered silver nanocluster/silica composite coatings on soda-lime glasses:ionic exchange and antibacterial activity (Articolo in rivista)
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- Effect of thermal treatments on sputtered silver nanocluster/silica composite coatings on soda-lime glasses:ionic exchange and antibacterial activity (Articolo in rivista) (literal)
- Anno
- 2012-01-01T00:00:00+01:00 (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
- 10.1007/s11051-012-1287-5 (literal)
- Alternative label
Ferraris, M.a, Ferraris, S.a , Miola, M.a, Perero, S.a, Balagna, C.a, Verné, E.a, Gautier, G.b, Manfredotti, Ch.c, Battiato, A.c, Vittone, E.c, Speranza, G.d, Bogdanovic, I.e (2012)
Effect of thermal treatments on sputtered silver nanocluster/silica composite coatings on soda-lime glasses:ionic exchange and antibacterial activity
in Journal of nanoparticle research; Springer Science+Business Media, Dordrecht (Germania)
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- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
- Ferraris, M.a, Ferraris, S.a , Miola, M.a, Perero, S.a, Balagna, C.a, Verné, E.a, Gautier, G.b, Manfredotti, Ch.c, Battiato, A.c, Vittone, E.c, Speranza, G.d, Bogdanovic, I.e (literal)
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- Silver nanocluster/silica composite coatings were
deposited in a less than two hours process on both
soda-lime and silica glasses by RF co-sputtering,
without densification post-treatment. The effect of
thermal treatments on their microstructure in the range
of 150-450 ?C, the presence of silver ions and/or
silver nanoclusters, the nanocluster size and their
position inside the sputtered layers have been investigated
by several characterization techniques (UV-
Vis, XPS, XRD, TOF-ERDA) which evidenced a
sodium/silver ionic exchange between the sputtered
coatings and the soda-lime substrates after heating up
to 450 ?C.
The antibacterial activity of all coatings was
verified against S. aureus and C. albicans by disk diffusion method and colonies forming units (CFU): in
agreement with the microstructural results, the antibacterial
activity present on all coatings was slightly
reduced after heating at 450 ?C. All coatings retained
their antibacterial activity after gamma ray and
ethylene oxide gas (EtO) sterilization. However, they
resulted damaged by humidity plus UV ageing and by
autoclave sterilization.
Tape resistance (ASTM D3359-97) nanoindentation
and scratch resistance tests have been done on
each coating, revealing a good adhesion on soda-lime
substrates and a reduced hardness of the coating
deposited on soda-lime substrates after heating at
450 ?C. (literal)
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- aDepartment of Applied Science and Technology, Institute of Materials Physics and Engineering, Politecnico di Torino, Turin, Italy
b IMAMOTER Institute for Agricultural and Earthmoving Machines, Turin, Italy
c Physics Department, NIS Excellence Centre and CNISM, University of Torino, Turin, Italy (literal)
- Titolo
- Effect of thermal treatments on sputtered silver nanocluster/silica composite coatings on soda-lime glasses:ionic exchange and antibacterial activity (literal)
- Abstract
- Silver nanocluster/silica composite coatings were deposited on both soda-lime and silica glasses by radio frequency (RF) co-sputtering. The effect of thermal treatments on the microstructure in the range of 150-450 °C were examined by UV- visible spectroscopy, X-ray diffraction, X-ray photoelectron spectroscopy and Time of Flight-Elastic Recoil Detection Analysis. Sodium/silver ionic exchange was evidenced for coatings sputtered on soda-lime substrates after heating at 450 °C; presence of silver ions and/or silver nanoclusters, nanocluster size and their position inside the sputtered layers will be discussed for as-deposited and heated coatings on both substrates. The antibacterial activity of all coatings was determined against Staphylococcus aureus and Candida albicans by disk diffusion method and colonies forming units count; in agreement with microstructural results, the antibacterial activity present on all coatings was slightly reduced after heating at 450 °C. All coatings have been submitted to humidity plus UV ageing and sterilization by autoclave, gamma ray and ethylene oxide gas. Tape resistance (ASTM D3359-97) tests have been done on each coating before and after ageing and sterilizations, revealing a good adhesion on soda-lime substrates, except for those aged in humidity plus UV and sterilized by autoclave. Scratch tests and nanoindentation tests have been done on each coating, as-deposited and after heating at 450 °C. The coating hardness was improved by heating only when coatings were deposited on silica. The heating of coatings deposited on soda-lime substrates gave opposite effect on their hardness. (literal)
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