Fabrication of Porous Semiconductor Interfaces by pH-Driven Assembly of Carbon Nanotubes on Honeycomb Structured Membranes (Articolo in rivista)

Type
Label
  • Fabrication of Porous Semiconductor Interfaces by pH-Driven Assembly of Carbon Nanotubes on Honeycomb Structured Membranes (Articolo in rivista) (literal)
Anno
  • 2013-01-01T00:00:00+01:00 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
  • 10.1021/jp405969b (literal)
Alternative label
  • Valentino Pingitore, Annarosa Gugliuzza (2013)
    Fabrication of Porous Semiconductor Interfaces by pH-Driven Assembly of Carbon Nanotubes on Honeycomb Structured Membranes
    in Journal of physical chemistry. C. (Online); ACS, American chemical society, Washington, DC (Stati Uniti d'America)
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Valentino Pingitore, Annarosa Gugliuzza (literal)
Pagina inizio
  • 26562 (literal)
Pagina fine
  • 26572 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#url
  • http://pubs.acs.org/doi/abs/10.1021/jp405969b (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 117 (literal)
Rivista
Note
  • ISI Web of Science (WOS) (literal)
  • Google Scholar (literal)
  • Scopus (literal)
  • PubMed (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • Dipartimento di Fisica, Università della Calabria, UNICAL Istituto per la Tecnologia delle Membrane, ITM-CNR (literal)
Titolo
  • Fabrication of Porous Semiconductor Interfaces by pH-Driven Assembly of Carbon Nanotubes on Honeycomb Structured Membranes (literal)
Abstract
  • emiconductor hybrid structures are achieved by interfacing single-walled carbon nanotubes (CNTs) with microstructured porous membranes. Interconnectivity and interplay of nanotubes are achieved by the assistance of adaptive polymers on 3D ordered honeycomb membranes. The buildup of semiconductor interfaces is based on the nanoassembly concept, which includes (a) self-assembly of sacrificial water droplets for tailoring 3D ordered polymeric platforms; (b) directed assembly of carbon nanotubes by sequential layer-by-layer (LBL) deposition; and (c) improvement of the electrical contact between nanotubes and stabilization of the organic-inorganic interface by pH- directed forces. Unprecedented better-quality charge-transfer pathways are achieved by making a large number of connections between nanotubes rather than increasing the adsorption of conductive inorganic materials onto the membrane platforms. Electrical current transfer is generated in hybrid interfaces, wherein fine conductivity function (? 102 S/m) is associated with high-defined porous structure, through a rationalization of the role of intermolecular forces in the assembly process. (literal)
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