Charge Transfer and Penning Ionization of Dopants in or on Helium Nanodroplets Exposed to EUV Radiation (Articolo in rivista)

Type
Label
  • Charge Transfer and Penning Ionization of Dopants in or on Helium Nanodroplets Exposed to EUV Radiation (Articolo in rivista) (literal)
Anno
  • 2013-01-01T00:00:00+01:00 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
  • 10.1021/jp401424w (literal)
Alternative label
  • Dominic Buchta +, Siva R. Krishnan ?, Nils B. Brauer ¶, Marcel Drabbels ¶, Patrick O'Keeffe §, Michele Devetta , Michele Di Fraia , Carlo Callegari #, Robert Richter #, Marcello Coreno §, Kevin C. Prince #, Frank Stienkemeier +, Robert Moshammer ?, and Marcel Mudrich *+ (2013)
    Charge Transfer and Penning Ionization of Dopants in or on Helium Nanodroplets Exposed to EUV Radiation
    in The journal of physical chemistry. A
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Dominic Buchta +, Siva R. Krishnan ?, Nils B. Brauer ¶, Marcel Drabbels ¶, Patrick O'Keeffe §, Michele Devetta , Michele Di Fraia , Carlo Callegari #, Robert Richter #, Marcello Coreno §, Kevin C. Prince #, Frank Stienkemeier +, Robert Moshammer ?, and Marcel Mudrich *+ (literal)
Pagina inizio
  • 4394 (literal)
Pagina fine
  • 4403 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#url
  • http://dx.doi.org/10.1021/jp401424w (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 117 (literal)
Rivista
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • + Physikalisches Institut, Universität Freiburg, 79104 Freiburg, Germany ? Max-Planck-Institut für Kernphysik, 69117 Heidelberg, Germany ¶ Laboratoire de Chimie Physique Moléculaire, Swiss Federal Institute of Technology Lausanne (EPFL), 1015 Lausanne, Switzerland § CNR Istituto di Metodologie Inorganiche e dei Plasmi, CP10, 00016 Monterotondo Scalo, Italy CIMAINA and Dipartimento di Fisica, Università di Milano, 20133 Milano, Italy Department of Physics, University of Trieste, 34128 Trieste, Italy # Elettra-Sincrotrone Trieste, 34149 Basovizza, Trieste, Italy (literal)
Titolo
  • Charge Transfer and Penning Ionization of Dopants in or on Helium Nanodroplets Exposed to EUV Radiation (literal)
Abstract
  • Helium nanodroplets are widely used as a cold, weakly interacting matrix for spectroscopy of embedded species. In this work, we excite or ionize doped He droplets using synchrotron radiation and study the effect onto the dopant atoms depending on their location inside the droplets (rare gases) or outside at the droplet surface (alkali metals). Using photoelectron-photoion coincidence imaging spectroscopy at variable photon energies (20-25 eV), we compare the rates of charge-transfer to Penning ionization of the dopants in the two cases. The surprising finding is that alkali metals, in contrast to the rare gases, are efficiently Penning ionized upon excitation of the (n = 2)-bands of the host droplets. This indicates rapid migration of the excitation to the droplet surface, followed by relaxation, and eventually energy transfer to the alkali dopants. (literal)
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