Electrosynthesis of Ni/Al and Mg/Al Layered Double Hydroxides on Pt and FeCrAlloy supports: Study and control of the pH near the electrode surface (Articolo in rivista)

Type

• Articolo in rivista (Classe)
• Prodotto della ricerca (Classe)

Label

• Electrosynthesis of Ni/Al and Mg/Al Layered Double Hydroxides on Pt and FeCrAlloy supports: Study and control of the pH near the electrode surface (Articolo in rivista) (literal)

Anno

• 2013-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1016/j.electacta.2013.06.143 (literal)

Alternative label

• Monti, M.a and Benito, P.a and Basile, F.a and Fornasari, G.a and Gazzano, M.b and Scavetta, E.a and Tonelli, D.a and Vaccari, A.a (2013)
  Electrosynthesis of Ni/Al and Mg/Al Layered Double Hydroxides on Pt and FeCrAlloy supports: Study and control of the pH near the electrode surface
  in Electrochimica acta
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Monti, M.a and Benito, P.a and Basile, F.a and Fornasari, G.a and Gazzano, M.b and Scavetta, E.a and Tonelli, D.a and Vaccari, A.a (literal)

Pagina inizio

• 596 (literal)

Pagina fine

• 604 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#altreInformazioni

• cited By (since 1996)0 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#url

• http://www.scopus.com/inward/record.url?eid=2-s2.0-84884242909&partnerID=40&md5=4e512b86a192072a358bd0009d75cb82 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 108 (literal)

Rivista

• Electrochimica acta (Rivista)

Note

• Scopu (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• Dipartimento di Chimica Industriale Toso Montanari, Università di Bologna, Viale Risorgimento 4, 40136 Bologna, Italy; ISOF-CNR, Via Selmi 2, 40126 Bologna, Italy (literal)

Titolo

• Electrosynthesis of Ni/Al and Mg/Al Layered Double Hydroxides on Pt and FeCrAlloy supports: Study and control of the pH near the electrode surface (literal)

Abstract

• The coating of substrate materials with different geometry (gauze, plate, foam) and composition (Pt and FeCrAlloy) with Layered Double Hydroxides (Ni/Al, Mg/Al) was performed using the base electrogeneration method. The pH established by the cathodic reduction of nitrates in the proximity of a Pt gauze was measured with a glass electrode. In order to study the morphology, composition, and structure of the electrodeposited solids, at first Pt plates were used as substrates; the characterization was performed by SEM/EDS and XRD. Lastly, the study was focused on the FeCrAlloy foam more complex substrate. The more negative the applied potential was, the higher the pH values measured were; however, very negative potentials (-1.1 to -1.3 V vs SCE) promoted the formation of H2 bubbles. Optimum potential for precipitating Layered Double Hydroxides depended on their chemical composition and even if the potential applied was adequate for the formation of pure phases, SEM/EDS analyses revealed that a sequential precipitation occurred at long synthesis times. © 2013 Published by Elsevier Ltd. (literal)

Prodotto di

• Polimerizzazione radicalica controllata e caratterizzazione avanzata di nuovi materiali polimerici (PRACCAMPO) (PM.P02.016.001) (Modulo)
• Institute for organic syntheses and photoreactivity (ISOF) (Istituto)

Autore CNR

• MASSIMO GAZZANO (Persona)

Insieme di parole chiave

• Parole chiave di "Electrosynthesis of Ni/Al and Mg/Al Layered Double Hydroxides on Pt and FeCrAlloy supports: Study and control of the pH near the electrode surface" (Insieme di parole chiave)

Incoming links:

Prodotto

• Institute for organic syntheses and photoreactivity (ISOF) (Istituto)
• Polimerizzazione radicalica controllata e caratterizzazione avanzata di nuovi materiali polimerici (PRACCAMPO) (PM.P02.016.001) (Modulo)

Autore CNR di

• MASSIMO GAZZANO (Persona)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Electrochimica acta (Rivista)

Insieme di parole chiave di

• Parole chiave di "Electrosynthesis of Ni/Al and Mg/Al Layered Double Hydroxides on Pt and FeCrAlloy supports: Study and control of the pH near the electrode surface" (Insieme di parole chiave)