Tethered ansa-bridged titanium complexes immobilized on 3-mercaptopropyl-functionalized silica gel and their application for the hydrosilylation of imines (Articolo in rivista)

Type

• Articolo in rivista (Classe)
• Prodotto della ricerca (Classe)

Label

• Tethered ansa-bridged titanium complexes immobilized on 3-mercaptopropyl-functionalized silica gel and their application for the hydrosilylation of imines (Articolo in rivista) (literal)

Anno

• 2012-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1039/c2dt31207g (literal)

Alternative label

• Gruber-Wölfler H., Neubauer C., Lichtenegger G.J., Polo E., Khinast J. (2012)
  Tethered ansa-bridged titanium complexes immobilized on 3-mercaptopropyl-functionalized silica gel and their application for the hydrosilylation of imines
  in Dalton transactions (2003. Print); ROYAL SOC CHEMISTRY, THOMAS GRAHAM HOUSE,, CAMBRIDGE CB4 0WF, CAMBS, ENGLAND (Regno Unito)
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Gruber-Wölfler H., Neubauer C., Lichtenegger G.J., Polo E., Khinast J. (literal)

Pagina inizio

• 12711 (literal)

Pagina fine

• 12719 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#url

• http://pubs.rsc.org/en/content/articlepdf/2012/DT/C2DT31207G (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 41 (literal)

Rivista

• Dalton transactions (Rivista)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#pagineTotali

• 9 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroFascicolo

• 41 (literal)

Note

• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• Gruber-Wölfler H., Neubauer C., Lichtenegger G.J., Khinast J., Graz Univ Technol, Inst Proc & Particle Engn, Polo E., ISOF - ISOF - Ferrara (literal)

Titolo

• Tethered ansa-bridged titanium complexes immobilized on 3-mercaptopropyl-functionalized silica gel and their application for the hydrosilylation of imines (literal)

Abstract

• Four tethered titanocene complexes were covalently immobilized onto 3-mercaptopropyl-functionalized silica gel. We have investigated the influence of the length of the tether and of the ansa-bridge on the activity in the heterogeneous hydrosilylation of the cyclic imine 2-phenylpyrroline, taken as an illustrative example. Possible metal leaching during the reaction was investigated using ICP/OES, recycling studies and the three-phase test. The novel immobilized catalysts exhibit an activity similar to their homogeneous analogues in the tested hydrosilylation reactions with a TOF of similar to 20 h(-1). Furthermore, our results indicate that metal leaching is negligible under the applied reaction conditions (literal)

Editore

• ROYAL SOC CHEMISTRY, THOMAS GRAHAM HOUSE, (Editore)

Prodotto di

• Sintesi e caratterizzazione mediante metodologie chimiche innovative, di scaffold molecolari per l'individuazione di nuove molecole biologicamente attive. (PM.P03.011.002) (Modulo)
• Institute for organic syntheses and photoreactivity (ISOF) (Istituto)
• Processi catalitici e foto(elettro)catalitici in sistemi organizzati e nanostrutturati (PM.P03.011.003) (Modulo)

Autore CNR

• ELEONORA POLO (Persona)

Insieme di parole chiave

• Keywords of "Tethered ansa-bridged titanium complexes immobilized on 3-mercaptopropyl-functionalized silica gel and their application for the hydrosilylation of imines" (Insieme di parole chiave)

Incoming links:

Prodotto

• Institute for organic syntheses and photoreactivity (ISOF) (Istituto)
• Sintesi e caratterizzazione mediante metodologie chimiche innovative, di scaffold molecolari per l'individuazione di nuove molecole biologicamente attive. (PM.P03.011.002) (Modulo)
• Processi catalitici e foto(elettro)catalitici in sistemi organizzati e nanostrutturati (PM.P03.011.003) (Modulo)

Autore CNR di

• ELEONORA POLO (Persona)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Dalton transactions (Rivista)

Editore di

• ROYAL SOC CHEMISTRY, THOMAS GRAHAM HOUSE, (Editore)

Insieme di parole chiave di

• Keywords of "Tethered ansa-bridged titanium complexes immobilized on 3-mercaptopropyl-functionalized silica gel and their application for the hydrosilylation of imines" (Insieme di parole chiave)