Bright, Fluorescent Dyes Based on Imidazo[1,2-a]pyridines that are Capable of Two-Photon Absorption (Articolo in rivista)

Type

• Prodotto della ricerca (Classe)
• Articolo in rivista (Classe)

Label

• Bright, Fluorescent Dyes Based on Imidazo[1,2-a]pyridines that are Capable of Two-Photon Absorption (Articolo in rivista) (literal)

Anno

• 2013-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1002/asia.201300058 (literal)

Alternative label

• Firmansyah, Dikhi and Ciuciu, Adina I. and Hugues, Vincent and Blanchard-Desce, Mireille and Flamigni, Lucia and Gryko, Daniel T. (2013)
  Bright, Fluorescent Dyes Based on Imidazo[1,2-a]pyridines that are Capable of Two-Photon Absorption
  in Chemistry - an Asian journal (Print)
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Firmansyah, Dikhi and Ciuciu, Adina I. and Hugues, Vincent and Blanchard-Desce, Mireille and Flamigni, Lucia and Gryko, Daniel T. (literal)

Pagina inizio

• 1279 (literal)

Pagina fine

• 1294 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 8 (literal)

Rivista

• Chemistry - an Asian journal (Rivista)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroFascicolo

• 6 (literal)

Note

• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• Warsaw University of Technology, Faculty of Chemistry, Noakowskiego 3, 00-664 Warsaw (Poland) Instituto per la Sintesi Organica e Fotoreattivita (ISOF), CNR, Via P. Gobetti 101, 40129 Bologna (Italy) Universit? de Bordeaux, ISM (UMR5255 CNRS), F 33400, Bordeaux (France) Institute of Organic Chemistry, Polish Academy of Sciences, Kasprzaka 44/52, Warsaw (Poland) (literal)

Titolo

• Bright, Fluorescent Dyes Based on Imidazo[1,2-a]pyridines that are Capable of Two-Photon Absorption (literal)

Abstract

• A library of imidazo[1,2-a]pyridines was synthesized by using the Gevorgyan method and their linear and non-linear optical properties were studied. Derivatives that contained both electron-donating and electron-withdrawing groups at the 2position were comprehensively investigated. Their emission quantum yield ranged between 0.20.7 and it was shown to depend on the substitution pattern, most notably that on the phenyl ring. Electron-donating substituents improved the luminescence performance of these compounds, whereas electron-withdrawing substituents led to a more erratic behavior. Substitution on the six-membered ring had less effect on the fluorescence properties. Extension of the delocalization increased the luminescence quantum yield. A new quadrupolar system was designed that contained two imidazo[1,2-a]pyridine units on its periphery and a 1,4-dicyanobenzene unit at its center. This system exhibited a large Stokes-shifted luminescence that was affected by the polarity and rigidity of the solvent, which was ascribed to emission from an excited state with strong charge-transfer character. This quadrupolar feature also led to an acceptable two-photon absorption response in the NIR region. (literal)

Prodotto di

• Materiali Avanzati per la COnversione di energia Luminosa (MACOL) (PM.P04.010.001) (Modulo)
• Institute for organic syntheses and photoreactivity (ISOF) (Istituto)

Autore CNR

• ADINA IULIANA CIUCIU (Unità di personale esterno)
• LUCIA FLAMIGNI (Unità di personale interno)

Incoming links:

Prodotto

• Institute for organic syntheses and photoreactivity (ISOF) (Istituto)
• Materiali Avanzati per la COnversione di energia Luminosa (MACOL) (PM.P04.010.001) (Modulo)

Autore CNR di

• LUCIA FLAMIGNI (Unità di personale interno)
• ADINA IULIANA CIUCIU (Unità di personale esterno)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Chemistry - an Asian journal (Rivista)