Third Order Non-Linear Optical Properties of Polyphenylene Vinylene Derivatives in the Infrared Range (Contributo in atti di convegno)

Type
Label
  • Third Order Non-Linear Optical Properties of Polyphenylene Vinylene Derivatives in the Infrared Range (Contributo in atti di convegno) (literal)
Anno
  • 2002-01-01T00:00:00+01:00 (literal)
Alternative label
  • Y. A. Dubitsky, A. Zaopo, A. Zappettini, G. Facchini, F. D'Amore, S. Pietralunga, M. Martinelli (2002)
    Third Order Non-Linear Optical Properties of Polyphenylene Vinylene Derivatives in the Infrared Range
    in Symposium on Electronic, Optical and Optoelectronic Polymers and Oligomers - Mat. Res. Soc., San Francisco, CA, USA, Apr. 17-20, 2001
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Y. A. Dubitsky, A. Zaopo, A. Zappettini, G. Facchini, F. D'Amore, S. Pietralunga, M. Martinelli (literal)
Pagina inizio
  • 23 (literal)
Pagina fine
  • 28 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#titoloVolume
  • ELECTRONIC, OPTICAL AND OPTOELECTRONIC POLYMERS AND OLIGOMERS (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#volumeInCollana
  • 665 (literal)
Note
  • ISI Web of Science (WOS) (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • Pirelli Cavi, CORECOM (literal)
Titolo
  • Third Order Non-Linear Optical Properties of Polyphenylene Vinylene Derivatives in the Infrared Range (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#isbn
  • 1-55899-601-X (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#curatoriVolume
  • Jabbour, GE; Sariciftci, NS (literal)
Abstract
  • The non-linear optical properties of poly[1,4-phenylene-1-phenyl vinylene], poly[1,4-phenylene-1,2-di(4'-phenoxyphenyl) vinylene], poly [2,5-dioctyloxy-1,4-phenylene vinylene] and poly[2-methoxy-5-(2'-ethylhexyloxy)-1,4-phenylene vinylene] MEH-PPV with different molecular weights were studied by the Third Harmonic Generation (THG) technique. The dispersion of the chi(3) coefficient was measured in the wide infra red range from 1.2 up to 2.1 mum. It was shown that the highest chi(3) value, observed for the high molecular weight MEH-PPV (Mw 230.000), reaches the maximum of 8x10(-11) esu at 1.77 mum. At the same time, the medium molecular weight MEH-PPV (Mw 95.000) demonstrated not significantly different chi(3) value of 6x10(-11) esu. The dispersion of the chi(3) coefficient was compared to the absorption of the third harmonic beam and strong chi(3) enhancement relative to the excitonic absorption was observed. However, a surprising shift of about 70 nm towards the longer wavelengths between the two peaks was always observed for all studied PPV derivatives. The results of THG measurements were compared to those obtained by conventional chi(3) scan technique in the same range. It was shown that the THG chi(3) Values in infrared range were up to one order of magnitude lower than those of direct Z-scan measurements. (literal)
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