Cross-linked poly-4-vinylpyridines as useful supports in metal catalysis: micro- and nanometer scale morphology (Articolo in rivista)

Type

• Prodotto della ricerca (Classe)
• Articolo in rivista (Classe)

Label

• Cross-linked poly-4-vinylpyridines as useful supports in metal catalysis: micro- and nanometer scale morphology (Articolo in rivista) (literal)

Anno

• 2007-01-01T00:00:00+01:00 (literal)

Alternative label

• Giammatteo, M; Tauro, L; D'Archivio, AA; Galantini, L; Panatta, A; Tettamanti, E; Jerabek, K; Corain, E (2007)
  Cross-linked poly-4-vinylpyridines as useful supports in metal catalysis: micro- and nanometer scale morphology
  
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Giammatteo, M; Tauro, L; D'Archivio, AA; Galantini, L; Panatta, A; Tettamanti, E; Jerabek, K; Corain, E (literal)

Pagina inizio

• 176 (literal)

Pagina fine

• 184 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 268 (literal)

Note

• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• Univ Aquila, Dipartimento Chim Ingn Chim & Mat, I-67100 Laquila, Italy; Univ Aquila, Ctr Electron Microscopy, I-67040 Laquila, Italy; Univ Padua, Dipartimento Mineral & Petrol, I-35137 Padua, Italy; Univ Roma La Sapienza, Dipartimento Chim, I-00185 Rome, Italy; Univ Aquila, Dipartimento Fis, INFM, I-67010 Coppito, Italy; Univ Teramo, Dipartimento Sci Biomed Comparate, I-64100 Teramo, Italy; Acad Sci Czech Republ, Inst Chem Proc Fundamentals, CR-16502 Prague 6, Czech Republic; CNR, Sez Padova, Dipartimento Sci Chim, Ist Sci & Tecnol Mol, I-35131 Padua, Italy (literal)

Titolo

• Cross-linked poly-4-vinylpyridines as useful supports in metal catalysis: micro- and nanometer scale morphology (literal)

Abstract

• Three commercially available poly-4-vinylpyridine resins, two of gel-type (2% cross-linked) and one macroreticular in nature (25% cross-linked) are investigated in the solid state with SEM and in the swollen state with a combination of inverse steric exclusion chromatography (ISEC) and ESR (test of rotational mobility of the spin probe TEMPONE) in various liquid media. In all cases the materials result to be scarcely swellable but, after iodomethylation they develope a quite noticeable nanoporosity in methanol, water and water/methanol/acetic acid. These observations are particularly valuable in the case of the resin Reilex 425 (Reilly Industries, Inc., USA) that is, in its iodomethylated form, the support of [Rh(CO)(2)I-2]-, i.e. the actual 'molecular' catalyst in the innovative Chiyoda-UOP industrial synthesis of acetic acid (Acetica process). (c) 2006 Elsevier B.V. All rights reserved. (literal)

Prodotto di

• Materia soffice: Self Assembly, Clustering, Arresto Strutturale (MD.P02.015.001) (Modulo)

Autore CNR

• Luciano GALANTINI (Unità di personale esterno)

Insieme di parole chiave

• Keywords of "Cross-linked poly-4-vinylpyridines as useful supports in metal catalysis: micro- and nanometer scale morphology" (Insieme di parole chiave)

Incoming links:

Autore CNR di

• Luciano GALANTINI (Unità di personale esterno)

Prodotto

• Materia soffice: Self Assembly, Clustering, Arresto Strutturale (MD.P02.015.001) (Modulo)

Insieme di parole chiave di

• Keywords of "Cross-linked poly-4-vinylpyridines as useful supports in metal catalysis: micro- and nanometer scale morphology" (Insieme di parole chiave)