http://www.cnr.it/ontology/cnr/individuo/prodotto/ID262009
Iron carbide nanoparticles growth in room temperature ionic liquids [C-n-MIM][BF4] (n=12, 16) (Articolo in rivista)
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- Iron carbide nanoparticles growth in room temperature ionic liquids [C-n-MIM][BF4] (n=12, 16) (Articolo in rivista) (literal)
- Anno
- 2013-01-01T00:00:00+01:00 (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
- 10.1007/s11051-013-1490-z (literal)
- Alternative label
Lartigue, L; Long, J; Dumail, X; Nikitenko, SI; Cau, C ; Guari, Y; Stievano, L; Sougrati, MT; Guerin, C; Sangregorio, C; Larionova, J (2013)
Iron carbide nanoparticles growth in room temperature ionic liquids [C-n-MIM][BF4] (n=12, 16)
in Journal of nanoparticle research; Springer, Dordrecht (Paesi Bassi)
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- Lartigue, L; Long, J; Dumail, X; Nikitenko, SI; Cau, C ; Guari, Y; Stievano, L; Sougrati, MT; Guerin, C; Sangregorio, C; Larionova, J (literal)
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- 1 ] Univ Montpellier 2, Inst Charles Gerhardt Montpellier, Chim Mol & Org Solide UMR5253, F-34095 Montpellier 5, France
2 ] CNR ISTM, I-20133 Milan, Italy
3 ] Univ Firenze, Dip Chim, INSTM Res Unit, I-50019 Sesto Fiorentino, Italy
4 ] Ctr Marcoule, UMR 5257, Inst Chim Separat Marcoule, F-30207 Bagnols Sur Ceze, France
5 ] Univ Montpellier 2, Inst Charles Gerhardt Montpellier, UMR Agregats Interfaces & Mat Energie 5243, F-34095 Montpellier 5, France (literal)
- Titolo
- Iron carbide nanoparticles growth in room temperature ionic liquids [C-n-MIM][BF4] (n=12, 16) (literal)
- Abstract
- The thermal decomposition of Fe-x(CO)(y) precursors for the synthesis of nanoparticles of iron carbides and their superstructures with sizes ranging from 2.8 to 15.1 nm is developed using imidazolium-based ionic liquids as solvents, stabilizers, and carbon source. A study of the influence of some synthesis parameters such as the heating temperature, nature, and concentration of the iron carbonyl precursor and chain length of the N-alkyl substituent on the imidazolium ring on the size and organization of the iron carbide nanoparticles is presented. These iron carbides nano-objects were characterized by infra-red spectroscopy, transmission electronic microscopy, powder X-ray diffraction, Mossbauer spectroscopy, and magnetic analyses. (literal)
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