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EDS, HRTEM/STEM, and X-ray Absorption Spectroscopy Studies of Co-Substituted Maghemite Nanoparticles (Articolo in rivista)
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- EDS, HRTEM/STEM, and X-ray Absorption Spectroscopy Studies of Co-Substituted Maghemite Nanoparticles (Articolo in rivista) (literal)
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- 2013-01-01T00:00:00+01:00 (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
- 10.1021/jp401706c (literal)
- Alternative label
Carta, D; Corrias, A; Falqui, A; Brescia, R; Fantechi, E; Pineider, F; Sangregorio, C (2013)
EDS, HRTEM/STEM, and X-ray Absorption Spectroscopy Studies of Co-Substituted Maghemite Nanoparticles
in Journal of physical chemistry. C; American Chemical Society, Washington (Stati Uniti d'America)
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- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
- Carta, D; Corrias, A; Falqui, A; Brescia, R; Fantechi, E; Pineider, F; Sangregorio, C (literal)
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- ISI Web of Science (WOS) (literal)
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- 1 ] Univ Cagliari, Dipartimento Sci Chim & Geol, I-09042 Cagliari, Italy
2 ] Univ Cagliari, INSTM, I-09042 Cagliari, Italy
3 ] Ist Italiano Tecnol, I-16163 Genoa, Italy
4 ] Univ Florence, INSTM, I-50019 Florence, Italy
5 ] Univ Florence, Dept Chem U Schiff, I-50019 Florence, Italy
6 ] Univ Padua, Dipartimento Sci Chim, CNR ISTM, I-35131 Padua, Italy
7 ] INSTM, I-35131 Padua, Italy
8 ] CNR ISTM, I-20133 Milan, Italy (literal)
- Titolo
- EDS, HRTEM/STEM, and X-ray Absorption Spectroscopy Studies of Co-Substituted Maghemite Nanoparticles (literal)
- Abstract
- A detailed study of the composition and structure of Co-doped maghemite nanoparticles with systematically varying composition has been carried out by transmission electron microscopy (TEM) techniques, such as high-resolution TEM, scanning TEM, and energy-dispersive X-ray spectrometry, and by X-ray absorption spectroscopy at the Fe and Co K-edges, analyzing both the extended X-ray absorption fine structure and the X-ray absorption near-edge structure regions. The latter techniques, in particular, allow us to determine the degree of inversion of divalent and trivalent metal ions among the octahedral and tetrahedral sites in the spinel structure of the nanoparticles and give detailed information on atomic distances. The samples consist of single-crystal nanoparticles with a composition corresponding to the Fe/Co ratio used in the synthesis. The degree of inversion is quite similar for all samples and close to the value found in a pure cobalt ferrite bulk sample. (literal)
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