On the way to graphene: The bottom up approach to very large PAHs using the scholl reaction (Articolo in rivista)

Type

• Articolo in rivista (Classe)
• Prodotto della ricerca (Classe)

Label

• On the way to graphene: The bottom up approach to very large PAHs using the scholl reaction (Articolo in rivista) (literal)

Anno

• 2011-01-01T00:00:00+01:00 (literal)

Alternative label

• F. Cataldo, O. Ursini , G. Angelini and S. Iglesias-Groth (2011)
  On the way to graphene: The bottom up approach to very large PAHs using the scholl reaction
  in Fullerenes, nanotubes, and carbon nanostructures (Print)
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• F. Cataldo, O. Ursini , G. Angelini and S. Iglesias-Groth (literal)

Pagina inizio

• 713 (literal)

Pagina fine

• 725 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 19 (literal)

Rivista

• Fullerenes, nanotubes, and carbon nanostructures (Rivista)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroFascicolo

• 8 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• Istituto Nazionale di Astrofisica, Osservatorio Astrofisica di Catania , Catania, Italy Lupi Chemical Research , Rome, Italy Institute of Chemical Methodologies , Rome, Italy Instituto de Astrofisica de Canarias , Tenerife, Spain (literal)

Titolo

• On the way to graphene: The bottom up approach to very large PAHs using the scholl reaction (literal)

Abstract

• The Scholl reaction was adopted to synthesize the very large polycyclic aromatic hydrocarbons (VLPAHs) hexabenzocoronene (HBC), quaterrylene and dicoronylene as well as their nonalternant isomers. These molecules can be considered subsections of a graphene sheet since the radial diameter of HBC is 13.5 Å and the length of both quaterrylene and dicoronylene is about 17.9 Å. Improved synthetic procedures of synthesis are presented, and the resulting VLPAHs were isolated and recognized from their characteristic electronic absorption spectra. The precursor PAHs used in the Scholl's synthesis where studied by differential scanning calorimetry (DSC), and the thermal behavior of the resulting VLPAHs was studied by thermogravimetric analysis and differential thermal analysis (TGA-DTA). The VLPAHs hexabenzocoronene (HBC), quaterrylene and dicoronylene show a trend to carbonization (growth of the laminar molecules into stacked and large graphene sheets) when heated slowly to high temperature in a nitrogen atmosphere. (literal)

Prodotto di

• Istituto di metodologie chimiche (IMC) (Istituto)
• Metodologie chimiche e radiochimiche per lo sviluppo di materiali e processi sostenibili (PM.P03.016.001) (Modulo)

Autore CNR

• ORNELLA URSINI (Unità di personale interno)
• GIANCARLO ANGELINI (Persona)

Incoming links:

Autore CNR di

• ORNELLA URSINI (Unità di personale interno)
• GIANCARLO ANGELINI (Persona)

Prodotto

• Istituto di metodologie chimiche (IMC) (Istituto)
• Metodologie chimiche e radiochimiche per lo sviluppo di materiali e processi sostenibili (PM.P03.016.001) (Modulo)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Fullerenes, nanotubes, and carbon nanostructures (Rivista)