Performance of vanadium based catalyst in a membrane contactor for the benzene hydroxylation to phenol (Articolo in rivista)

Type

• Articolo in rivista (Classe)
• Prodotto della ricerca (Classe)

Label

• Performance of vanadium based catalyst in a membrane contactor for the benzene hydroxylation to phenol (Articolo in rivista) (literal)

Anno

• 2012-01-01T00:00:00+01:00 (literal)

Alternative label

• Raffaele Molinari*, Cristina Lavorato, Teresa Poerio (2012)
  Performance of vanadium based catalyst in a membrane contactor for the benzene hydroxylation to phenol
  in Applied catalysis. A, General (Print)
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Raffaele Molinari*, Cristina Lavorato, Teresa Poerio (literal)

Pagina inizio

• 87 (literal)

Pagina fine

• 92 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 417-418 (literal)

Rivista

• Applied catalysis. A, General (Rivista)

Note

• ISI Web of Science (WOS) (literal)
• Scopus (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• Department of Chemical Engineering and Materials, - UdR INCA, University of Calabria, Via P. Bucci, 44/A, I-87036 Rende (CS), Italy (literal)

Titolo

• Performance of vanadium based catalyst in a membrane contactor for the benzene hydroxylation to phenol (literal)

Abstract

• Phenol production through the direct hydroxylation of benzene with hydrogen peroxide, as oxidant, using a vanadium catalyst in a membrane reactor has been studied. The reaction was carried out in mild condition in a liquid-liquid biphasic system separated by a polypropylene membrane. This system showed high selectivity to phenol, minimizing its over-oxidation to over-oxygenated by-products. The influence of various reaction parameters such as the addition of hydrogen peroxide mode, catalyst and sulphuric acid amounts, temperature and reducing agent effects were investigated. The vanadium catalyst avoided tar formation in all the investigated experimental conditions compared to the previous system where an iron-based catalyst was used. Use of (C5H8O2)2VO as catalyst, 18 mmol of hydrogen peroxide as oxidant pumped for 4 h in the aqueous phase with the step-by-step feeding mode gave the best system performance in terms of yield (63.2%), selectivity to phenol (97.0%), and extraction quotient (76.4%). (literal)

Prodotto di

• Membrane in Separazioni Gassose e Catalisi anche ad alta temperatura in processi di interesse industriale (PM.P02.007.007) (Modulo)
• Institute on membrane technology (ITM) (Istituto)

Autore CNR

• TERESA POERIO (Unità di personale interno)

Incoming links:

Prodotto

• Institute on membrane technology (ITM) (Istituto)
• Membrane in Separazioni Gassose e Catalisi anche ad alta temperatura in processi di interesse industriale (PM.P02.007.007) (Modulo)

Autore CNR di

• TERESA POERIO (Unità di personale interno)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Applied catalysis. A, General (Rivista)