An expedient preparation of enantio-enriched ambergris odorants starting from commercial ionone alpha (Articolo in rivista)

Type
Label
  • An expedient preparation of enantio-enriched ambergris odorants starting from commercial ionone alpha (Articolo in rivista) (literal)
Anno
  • 2013-01-01T00:00:00+01:00 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
  • 10.1002/ffj.3126 (literal)
Alternative label
  • Serra Stefano (2013)
    An expedient preparation of enantio-enriched ambergris odorants starting from commercial ionone alpha
    in Flavour and fragrance journal (Print)
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Serra Stefano (literal)
Pagina inizio
  • 46 (literal)
Pagina fine
  • 52 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 28 (literal)
Rivista
Note
  • ISI Web of Science (WOS) (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • CNR-ICRM (literal)
Titolo
  • An expedient preparation of enantio-enriched ambergris odorants starting from commercial ionone alpha (literal)
Abstract
  • We report the enantioselective synthesis of the ambergris odorants (+)-(S)--ionone, (+)-(S)--dihydroionone, (-)--ambrinol, (+)-(S)--coronal, (-)-(S)--homocyclogeranyl chloride and (+)-(S)--homocyclogeraniol. At first, the enantio-enriched (4R,6S)-4-acetoxy--ionone was prepared starting from commercial racemic ionone alpha by means of a chemo-enzymatic process. This chiral building block was then converted into (S)--dihydroionone which was used as the starting material for the synthesis of the aforementioned odorants. (literal)
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