Base-Induced Cycloaddition of Tosylmethyl or (tert-Butoxycarbonyl)methyl Isocyanide to 1,4-Disubstituted 2,3-Dinitro-1,3-butadienes. Access to 2,3-Disubstituted 4-Ethynylpyrroles (Articolo in rivista)

Type

• Prodotto della ricerca (Classe)
• Articolo in rivista (Classe)

Label

• Base-Induced Cycloaddition of Tosylmethyl or (tert-Butoxycarbonyl)methyl Isocyanide to 1,4-Disubstituted 2,3-Dinitro-1,3-butadienes. Access to 2,3-Disubstituted 4-Ethynylpyrroles (Articolo in rivista) (literal)

Anno

• 1995-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1016/0040-4020(95) (literal)

Alternative label

• Dell'Erba C.; Giglio A.; Mugnoli A.; Novi M.; Petrillo G.; Stagnaro P. (1995)
  Base-Induced Cycloaddition of Tosylmethyl or (tert-Butoxycarbonyl)methyl Isocyanide to 1,4-Disubstituted 2,3-Dinitro-1,3-butadienes. Access to 2,3-Disubstituted 4-Ethynylpyrroles
  in Tetrahedron (Oxf., Print); PERGAMON-ELSEVIER SCIENCE LTD, THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD (Regno Unito)
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Dell'Erba C.; Giglio A.; Mugnoli A.; Novi M.; Petrillo G.; Stagnaro P. (literal)

Pagina inizio

• 5181 (literal)

Pagina fine

• 5192 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#url

• http://ac.els-cdn.com/004040209598713R/1-s2.0-004040209598713R-main.pdf?_tid=6ea57dba-0010-11e3-bdab-00000aab0f27&acdnat=1375955812_2f55c8cd50ca579c6eefa5c84acaff43 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 51 (literal)

Rivista

• Tetrahedron (Rivista)

Note

• ISI Web of Science (WOS) (literal)
• Scopu (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• Dell'Erba C.; Giglio A.; Mugnoli A.; Novi M.; Petrillo G. Università di Genova Stagnaro P. Università di Genova (attualmente CNR-ISMAC Genova) (literal)

Titolo

• Base-Induced Cycloaddition of Tosylmethyl or (tert-Butoxycarbonyl)methyl Isocyanide to 1,4-Disubstituted 2,3-Dinitro-1,3-butadienes. Access to 2,3-Disubstituted 4-Ethynylpyrroles (literal)

Abstract

• The reactions of 1,4-disubstituted 23-dinitro-1,3-butadienes 1a-g in THF with isocyanides XCH(2)NC (TosMIC, X = tosyl; TBICA, X = COOBu(t)) and DBU furnish good to moderate yields of 2,3-disubstituted 4- ethynylpyrroles 5a-g or 6a-g. In the reaction of Ig with TosMIC and DBU the nitrovinyl pyrrole 7g and the 3,3'-dipyrrole 4g are also isolated as by-products. A mechanism involving sequential base-induced addition, elimination and cyclization steps is advanced to account for the formation of the isolated products. (literal)

Editore

• PERGAMON-ELSEVIER SCIENCE LTD (Editore)

Prodotto di

• Istituto per lo studio delle macromolecole (ISMAC) (Istituto)
• Progettazione e sviluppo di materiali polimerici multifasici micro e nanostrutturati (PM.P02.005.004) (Modulo)

Autore CNR

• PAOLA STAGNARO (Persona)

Incoming links:

Prodotto

• Istituto per lo studio delle macromolecole (ISMAC) (Istituto)
• Progettazione e sviluppo di materiali polimerici multifasici micro e nanostrutturati (PM.P02.005.004) (Modulo)

Autore CNR di

• PAOLA STAGNARO (Persona)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Tetrahedron (Rivista)

Editore di

• PERGAMON-ELSEVIER SCIENCE LTD (Editore)