http://www.cnr.it/ontology/cnr/individuo/prodotto/ID237367
Identification of Nd163 Phase in Melt-Textured NdBa2Cu3O7+x/2-d Bulk Samples (Articolo in rivista)
- Type
- Label
- Identification of Nd163 Phase in Melt-Textured NdBa2Cu3O7+x/2-d Bulk Samples (Articolo in rivista) (literal)
- Anno
- 2003-01-01T00:00:00+01:00 (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
- 10.1557/JMR.2003.0288 (literal)
- Alternative label
Marcello Gombos, Vicente Gomis, Anna Esther Carrillo, Antonio Vecchione, Sandro Pace, and Xavier Obradors (2003)
Identification of Nd163 Phase in Melt-Textured NdBa2Cu3O7+x/2-d Bulk Samples
in Journal of materials research; Materials Research Society, Pittsburgh, PA (Stati Uniti d'America)
(literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
- Marcello Gombos, Vicente Gomis, Anna Esther Carrillo, Antonio Vecchione, Sandro Pace, and Xavier Obradors (literal)
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- Università di Salerno, INFM, Universitat Politecnica de Catalunya, ICMAB-CSIC (literal)
- Titolo
- Identification of Nd163 Phase in Melt-Textured NdBa2Cu3O7+x/2-d Bulk Samples (literal)
- Abstract
- In this work, we report on the observation of Nd1Ba6Cu3O10,5 (Nd163) phase of the NdBaCuO system in melt-textured Nd123 bulk samples grown from a mixture of Nd123 and Nd210 phase powders. The observation was performed with polarized light optical microscopy and scanning electron microscopy-energy dispersive x-ray analyses. Images of the identified phase crystals show an aspect quite different from Nd422 crystals. Unexpectedly, Nd163 was individuated, even in \"pure\" Nd123 samples. Moreover, after long exposure to air, Nd163 disappeared completely in samples synthesized from powders containing Nd210. Thermogravimetry analyses of powders show that the stability of this phase in air is limited to temperatures higher than 900 °C, so Nd163 is unstable and highly reactive at room temperature. Moreover, an explanation of the observation of Nd163 in Nd210 free samples, based on the spontaneous formation of Nd163 phase in a Nd123 melt, is proposed. (literal)
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