Further-Studies on the Composition And Microstructure of Copolymers by Statistical Modeling of their Mass-Spectra (Articolo in rivista)

Type

• Prodotto della ricerca (Classe)
• Articolo in rivista (Classe)

Label

• Further-Studies on the Composition And Microstructure of Copolymers by Statistical Modeling of their Mass-Spectra (Articolo in rivista) (literal)

Anno

• 1992-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1021/ma00043a005 (literal)

Alternative label

• MONTAUDO MS, MONTAUDO G, (1992)
  Further-Studies on the Composition And Microstructure of Copolymers by Statistical Modeling of their Mass-Spectra
  in Macromolecules (Print); ACS, American chemical society, Washington, DC (Stati Uniti d'America)
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• MONTAUDO MS, MONTAUDO G, (literal)

Pagina inizio

• 4264 (literal)

Pagina fine

• 4280 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 25 (literal)

Rivista

• Macromolecules (Rivista)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#pagineTotali

• 15 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroFascicolo

• 17 (literal)

Note

• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• polimeri (literal)

Titolo

• Further-Studies on the Composition And Microstructure of Copolymers by Statistical Modeling of their Mass-Spectra (literal)

Abstract

• Abstract: Statistical modeling of the mass spectral intensities of copolymers has been used to derive information on the distribution of monomers along the copolymer chain, and an automated procedure to find the composition and the sequence of the copolymers analyzed has been developed. A deconvolution method to determine the microstructure of copolymers when different chemical species contribute to the same mass spectral peak (that is, when a mass spectroscopic peak has an equivocal structural assignment) is presented. The effect of the partial degradation process on the mass spectra of copolymers is discussed, and a theory is given for the interpretation of the mass spectra of copolymers when the cleavage of the copolymer chain occurs by a selective or nonselective mechanism. A method is also reported to obtain the copolymer composition by direct analysis of the mass spectra. All these theories have been applied to determine the composition and microstructure of several copolymers (both addition and condensation types) whose mass spectra have been reported in the most recent literature. (literal)

Editore

• ACS, American chemical society (Editore)

Prodotto di

• Istituto di chimica e tecnologia dei polimeri (ICTP) (Istituto)

Autore CNR

• MAURIZIO MONTAUDO (Unità di personale interno)

Incoming links:

Autore CNR di

• MAURIZIO MONTAUDO (Unità di personale interno)

Prodotto

• Istituto di chimica e tecnologia dei polimeri (ICTP) (Istituto)

Editore di

• ACS, American chemical society (Editore)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Macromolecules (Rivista)