Cu/SiO2 and Cu/SiO2-TiO2 catalysts. II. Identification of the active sites in the polymerization of 2,6-dimethylphenol in the presence of molecular oxygen (Articolo in rivista)

Type

• Prodotto della ricerca (Classe)
• Articolo in rivista (Classe)

Label

• Cu/SiO2 and Cu/SiO2-TiO2 catalysts. II. Identification of the active sites in the polymerization of 2,6-dimethylphenol in the presence of molecular oxygen (Articolo in rivista) (literal)

Anno

• 1999-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1006/jcat.1999.2429 (literal)

Alternative label

• F.Boccuzzi, G.Martra, C.Partipilo Papalia, Nicoletta Ravasio (1999)
  Cu/SiO2 and Cu/SiO2-TiO2 catalysts. II. Identification of the active sites in the polymerization of 2,6-dimethylphenol in the presence of molecular oxygen
  in Journal of catalysis (Print); Academic Press, San Diego (Stati Uniti d'America)
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• F.Boccuzzi, G.Martra, C.Partipilo Papalia, Nicoletta Ravasio (literal)

Pagina inizio

• 327 (literal)

Pagina fine

• 334 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 184 (literal)

Rivista

• Journal of catalysis (Rivista)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#pagineTotali

• 8 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroFascicolo

• 2 (literal)

Note

• ISI Web of Science (WOS) (literal)
• Scopu (literal)
• SCImago (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• Dipartimento di Chimica I.F.M., Università di Torino, Via P. Giuria 7, I-10125 Turin, Italy Dipartimento di Chimica, Universitá di Bari, Via Orabona 4, I-70126 Bari, Italy C.N.R. CSSCMTBO, C/o Dipartimento di Chimica I. M. A., Università di Milano, Via Venezian 21, I-20133 Milan, Italy (literal)

Titolo

• Cu/SiO2 and Cu/SiO2-TiO2 catalysts. II. Identification of the active sites in the polymerization of 2,6-dimethylphenol in the presence of molecular oxygen (literal)

Abstract

• 8% Cu/SiO2 and Cu/SiO2-TiO2 catalysts, prepared by the chemisorption hydrolysis method and characterised in the preceding paper (Boccuzzi et al., 1999, J. Catal., 184, 316-326) have been tested in the oxidative coupling of 2,6-dimethylphenol, a well-known copper catalysed reaction in the homogeneous phase. All of them proved to be active after reduction of the copper oxide initially present giving similar to 75% of PPE and <4% DPQ. Although they lost similar to 30% of the metal during the first run, they appeared to be reusable and more active during the second run. From HRTEM and FTIR characterisation before and after the polymerisation reaction, it can be deduced that three-dimensional copper particles are preferentially leached under the reaction conditions, while electron deficient two-dimensional metallic particles can be responsible for the catalytic activity. (literal)

Editore

• Academic Press (Editore)

Prodotto di

• Istituto di scienze e tecnologie molecolari (ISTM) (Istituto)
• Processi chimici per la bioraffineria (PM.P03.004.002) (Modulo)

Autore CNR

• MARIA NICOLETTA RAVASIO (Persona)

Insieme di parole chiave

• Keywords of "Cu/SiO2 and Cu/SiO2-TiO2 catalysts. II. Identification of the active sites in the polymerization of 2,6-dimethylphenol in the presence of molecular oxygen" (Insieme di parole chiave)

Incoming links:

Prodotto

• Istituto di scienze e tecnologie molecolari (ISTM) (Istituto)
• Processi chimici per la bioraffineria (PM.P03.004.002) (Modulo)

Autore CNR di

• MARIA NICOLETTA RAVASIO (Persona)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Journal of catalysis (Rivista)

Editore di

• Academic Press (Editore)

Insieme di parole chiave di

• Keywords of "Cu/SiO2 and Cu/SiO2-TiO2 catalysts. II. Identification of the active sites in the polymerization of 2,6-dimethylphenol in the presence of molecular oxygen" (Insieme di parole chiave)